The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Insight into the Electrode Mechanism in Lithium‐Sulfur Batteries with Ordered Microporous Carbon Confined Sulfur as the Cathode
Abstract
In lithium‐sulfur batteries, small S 2–4 molecules show very different electrochemical responses from the traditional S 8 material. Their exact lithiation/delitiation mechanism is not clear and how to select proper electrolytes for the S 2–4 cathodes is also ambiguous. Here, S 2–4 and S 8/S 2–4 composites with highly ordered microporous carbon as a confining matrix are fabricated and the electrode mechanism of the S 2–4 cathode is investigated by comparing the electrochemical performances of the S 2–4 and S 2–4/S 8 electrodes in various electrolytes combined with theoretical calculation. Experimental results show that the electrolyte and microstructure of carbon matrix play important roles in the electrochemical performance. If the micropores of carbon are small enough to prevent the penetration of the solvent molecules, the lithiation/delithiation for S 2–4 occurs as a solid‐solid process. The irreversible chemically reactions between the polysulfudes and carbonates, and the dissolution of the polysulfides into the ethers can be effectively avoided due to the steric hindrance. The confined S 2–4 show high adaptability to the electrolytes. The sulfur cathode based on this strategy exhibits excellent rate capability and cycling stability.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries
Ji, X., Lee, K. T., & Nazar, L. F. (2009) · Nature Materials · doi:10.1038/nmat2460 · Cited by 5,988
Challenges and Prospects of Lithium–Sulfur Batteries
Manthiram, A., Fu, Y., & Su, Y.-S. (2013) · Accounts of Chemical Research · doi:10.1021/ar300179v · Cited by 2,380
Ji, X., & Nazar, L. F. (2010) · Journal of Materials Chemistry · doi:10.1039/b925751a · Cited by 1,967
Porous Hollow Carbon@Sulfur Composites for High‐Power Lithium–Sulfur Batteries
Jayaprakash, N., Shen, J., Moganty, S. S., Corona, A., & Archer, L. A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201100637 · Cited by 1,811
Smaller Sulfur Molecules Promise Better Lithium–Sulfur Batteries
Xin, S., Gu, L., Zhao, N.-H., Yin, Y.-X., Zhou, L.-J., Guo, Y.-G., & Wan, L.-J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja308170k · Cited by 1,644
Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer
Su, Y.-S., & Manthiram, A. (2012) · Nature Communications · doi:10.1038/ncomms2163 · Cited by 1,458
New Approaches for High Energy Density Lithium–Sulfur Battery Cathodes
Evers, S., & Nazar, L. F. (2013) · Accounts of Chemical Research · doi:10.1021/ar3001348 · Cited by 1,324
Zhang, B., Qin, X., Li, G. R., & Gao, X. P. (2010) · Energy & Environmental Science · doi:10.1039/c002639e · Cited by 1,280
Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium–Sulfur Batteries
Schuster, J., He, G., Mandlmeier, B., Yim, T., Lee, K. T., Bein, T., & Nazar, L. F. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201107817 · Cited by 1,114
Cited by
Review on High‐Loading and High‐Energy Lithium–Sulfur Batteries
Peng, H., Huang, J., Cheng, X., & Zhang, Q. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201700260 · Cited by 1,746
Liu, D., Zhang, C., Zhou, G., Lv, W., Ling, G., Zhi, L., & Yang, Q. (2018) · Advanced Science · doi:10.1002/advs.201700270 · Cited by 956
Wei, Q., Xiong, F., Tan, S., Huang, L., Lan, E. H., Dunn, B., & Mai, L. (2017) · Advanced Materials · doi:10.1002/adma.201602300 · Cited by 802
Pyrite FeS2for high-rate and long-life rechargeable sodium batteries
Hu, Z., Zhu, Z., Cheng, F., Zhang, K., Wang, J., Chen, C., & Chen, J. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03759f · Cited by 686
Carbon materials for Li–S batteries: Functional evolution and performance improvement
Liang, J., Sun, Z.-H., Li, F., & Cheng, H.-M. (2016) · Energy Storage Materials · doi:10.1016/j.ensm.2015.09.007 · Cited by 593
Metadata
- Authors
- Li, Z., Yuan, L., Yi, Z., Sun, Y., Liu, Y., Jiang, Y., Shen, Y., Xin, Y., Zhang, Z., & Huang, Y.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2013-11-27
- Volume
- 4
- Issue
- 7
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2086802347
- Cited by
- 481
- References
- 31
- FWCI
- 21.17
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Insight into the Electrode Mechanism in Lithium‐Sulfur Batteries with Ordered Microporous Carbon Confined Sulfur as the Cathode. https://app.cochat.ai/papers/10.1002/aenm.201301473
- The paper
- Li, Z., Yuan, L., Yi, Z., Sun, Y., Liu, Y., Jiang, Y., Shen, Y., Xin, Y., Zhang, Z., & Huang, Y. (2014). Insight into the Electrode Mechanism in Lithium‐Sulfur Batteries with Ordered Microporous Carbon Confined Sulfur as the Cathode. Advanced Energy Materials. https://doi.org/10.1002/aenm.201301473
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
