The DOI matches its Crossref record; 161 of the 161 references it cites were found in a registry or an index.
Thiol‐En‐Klickchemie
Abstract
Nach Sharpless’ visionärer Charakterisierung verschiedener idealisierter Reaktionen als Klick‐Reaktionen hat man innerhalb der Materialwissenschaften und Synthesechemie große Anstrengungen unternommen, um solche Reaktionen zu finden und zu implementieren. In diesem Aufsatz diskutieren wir die radikalvermittelte Thiol‐En‐Reaktion, die über all die Merkmale einer Klick‐Reaktion verfügt: hohe Effizienz, einfache Durchführung, keine Nebenprodukte, hohe Reaktionsgeschwindigkeiten, hohe Ausbeuten. Darüber hinaus besteht die Möglichkeit, die Thiol‐En‐Reaktion photoinitiiert auszuführen, was insbesondere für Photopolymerisationen zur Synthese extrem einheitlicher Polymernetzwerke genutzt wird. Der Reaktionsmechanismus wird nach dem aktuellen Kenntnisstand erläutert, und zentrale Anwendungen der Thiol‐En‐Reaktion in der Material‐ und Molekülsynthese, der Biofunktionalisierung, der Polymersynthese und der Oberflächen‐ und Polymermodifizierung werden zusammengefasst.
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Citations
Cites
Click-Chemie: diverse chemische Funktionalität mit einer Handvoll guter Reaktionen
Kolb, H. C., Finn, M. G., & Sharpless, K. B. (2001) · Angewandte Chemie · doi:10.1002/1521-3757(20010601)113:11<2056::aid-ange2056>3.0.co;2-w · Cited by 1,624
‘Click’ Chemistry in Polymer and Materials Science
Binder, W. H., & Sachsenhofer, R. (2007) · Macromolecular Rapid Communications · doi:10.1002/marc.200600625 · Cited by 1,561
Thiol–enes: Chemistry of the past with promise for the future
Hoyle, C. E., Lee, T. Y., & Roper, T. (2004) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20366 · Cited by 1,457
Self-citationMichael addition reactions in macromolecular design for emerging technologies
Mather, B. D., Viswanathan, K., Miller, K. M., & Long, T. E. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.03.001 · Cited by 1,127
Photonic-crystal full-colour displays
Arsenault, A. C., Puzzo, D. P., Manners, I., & Ozin, G. A. (2007) · Nature Photonics · doi:10.1038/nphoton.2007.140 · Cited by 914
Click Chemistry beyond Metal‐Catalyzed Cycloaddition
Becer, C. R., Hoogenboom, R., & Schubert, U. S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200900755 · Cited by 866
Sequential click reactions for synthesizing and patterning three-dimensional cell microenvironments
DeForest, C. A., Polizzotti, B. D., & Anseth, K. S. (2009) · Nature Materials · doi:10.1038/nmat2473 · Cited by 847
Robust, Efficient, and Orthogonal Synthesis of Dendrimers via Thiol-ene “Click” Chemistry
Killops, K. L., Campos, L. M., & Hawker, C. J. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8006325 · Cited by 792
Photoinduced Plasticity in Cross-Linked Polymers
Scott, T. F., Schneider, A. D., Cook, W. D., & Bowman, C. N. (2005) · Science · doi:10.1126/science.1110505 · Cited by 776
Self-citationKinetic Study and New Applications of UV Radiation Curing
Decker, C. (2002) · Macromolecular Rapid Communications · doi:10.1002/marc.200290014 · Cited by 688
Cited by
Thiol–Ene Clickable Gelatin: A Platform Bioink for Multiple 3D Biofabrication Technologies
Bertlein, S., Brown, G., Lim, K. S., Jungst, T., Boeck, T., Blunk, T., Tessmar, J., Hooper, G. J., Woodfield, T. B. F., & Groll, J. (2017) · Advanced Materials · doi:10.1002/adma.201703404 · Cited by 331
Photoreversible Patterning of Biomolecules within Click‐Based Hydrogels
DeForest, C. A., & Anseth, K. S. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201106463 · Cited by 315
Metadata
- Authors
- Hoyle, C. E., & Bowman, C. N.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2010-02-17
- Volume
- 122
- Issue
- 9
- Pages
- 1584-1617
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W2156564718
- Cited by
- 293
- References
- 161
- FWCI
- 10.89
- Type
- journal article
- Language
- de
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
