The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Organic‐Base‐Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance
Abstract
The delamination of titanium carbide sheets, an intriguing class of two‐dimensional materials, has been critically dependent on the extraction of interlayer Al in acidic media, such as concentrated hydrofluoric acid (HF) or a mixture of hydrochloric acid (HCl) and a fluoride salt. Herein, we report an organic‐base‐driven intercalation and delamination of titanium carbide that takes advantage of the amphoteric nature of interlayer Al. The resulting aluminum‐oxoanion‐functionalized titanium carbide sheets manifested unusually strong optical absorption in the near‐infrared (NIR) region with a mass extinction coefficient as high as 29.1 L g−1 cm−1 at 808 nm. Thus, the performance of this material is comparable or even superior to that of state‐of‐the‐art photoabsorption materials, including gold‐based nanostructures, carbon‐based materials, and transition‐metal dichalcogenides. Preliminary studies show that the titanium carbide sheets serve as efficient photothermal agents against tumor cells.
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Cites
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
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Intercalation and delamination of layered carbides and carbonitrides
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Self-citationGraphene in Mice: Ultrahigh In Vivo Tumor Uptake and Efficient Photothermal Therapy
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Cited by
Fluorine‐Free Synthesis of High‐Purity Ti3C2Tx (T=OH, O) via Alkali Treatment
Li, T., Yao, L., Liu, Q., Gu, J., Luo, R., Li, J., Yan, X., Wang, W., Liu, P., Chen, B., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201800887 · Cited by 1,457
Selective Etching of Silicon from Ti3SiC2 (MAX) To Obtain 2D Titanium Carbide (MXene)
Alhabeb, M., Maleski, K., Mathis, T. S., Sarycheva, A., Hatter, C. B., Uzun, S., Levitt, A., & Gogotsi, Y. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802232 · Cited by 452
Rational Design of Biomaterials to Potentiate Cancer Thermal Therapy
Zhu, Y., Li, Q., Wang, C., Hao, Y., Yang, N., Chen, M., Ji, J., Feng, L., & Liu, Z. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00822 · Cited by 163
Self-citationTitanium carbide nanosheets with defect structure for photothermal-enhanced sonodynamic therapy
Li, G., Zhong, X., Wang, X., Gong, F., Lei, H., Zhou, Y., Li, C., Xiao, Z., Ren, G., Zhang, L., et al. (2022) · Bioactive Materials · doi:10.1016/j.bioactmat.2021.06.021 · Cited by 151
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Metadata
- Authors
- Xuan, J., Wang, Z., Chen, Y., Liang, D., Cheng, L., Yang, X., Liu, Z., Ma, R., Sasaki, T., & Geng, F.
- Venue
- Angewandte Chemie
- Publisher
- Wiley
- Published
- 2016-10-24
- Volume
- 128
- Issue
- 47
- Pages
- 14789-14794
- ISSN
- 0044-8249 (ISSN-L)
- 1521-3757
- OpenAlex
- W4229623802
- Cited by
- 259
- References
- 29
- FWCI
- 7.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xuan, J., Wang, Z., Chen, Y., Liang, D., Cheng, L., Yang, X., Liu, Z., Ma, R., Sasaki, T., & Geng, F. (2016). Organic‐Base‐Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance. Angewandte Chemie. https://doi.org/10.1002/ange.201606643
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