Cited by 70Organometallic Complex Synthesis and CatalysisAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

Alternating Copolymerization of Ethylene and Butadiene with a Neodymocene Catalyst

Thuilliez, Julien, Monteil, Vincent, Spitz, Roger, Boisson, Christophe·2005·Angewandte Chemie International Edition

Abstract

A new route to poly(ethylene-alt-butadiene) uses a homogeneous neodymocene/dialkylmagnesium catalyst which exhibits high activity and allows the polymerization to be easily controlled, both in terms of molecular weight and microstructure of the product. The s-trans-η4-butadiene complex shown in the picture is thought to be an essential intermediate of this reaction.

Integrity signals

Registry

Crossref · 10.1002/anie.200462019

Cites

23 of 23 references verified0 citation errors · 0 not checkable

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Cites

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1 of the 24 references couldn’t be matched to a known paper.

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Authors
Thuilliez, J., Monteil, V., Spitz, R., & Boisson, C.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
Boisson, Christophe
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2005-04-21
Volume
44
Issue
17
Pages
2593-2596
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2026531448
Cited by
70
References
24
Citations by year
2026: 2 · 2025: 3 · 2024: 5 · 2023: 2 · 2022: 2 · 2021: 4 · 2020: 1 · 2019: 3 · 2018: 5 · 2017: 6 · 2015: 2 · 2014: 3 · 2013: 3 · 2012: 3
FWCI
2.99
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
  • HAL (submittedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Keywords
alternating copolymerization, ethylene, 1,3-butadiene, dialkylmagnesium, homogeneous catalysis, polymer microstructure control, molecular weight control

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