Stereoselective Cyclopropanation by Cyclocopolymerization of Butadiene
Abstract
An unprecedented cyclopropanation by cyclopolymerization reaction is presented. In particular, catalytic copolymerization processes of ethene and butadiene lead with high trans selectivity to a complete cyclocopolymerization of butadiene units. Ethene-based copolymers including cyclopropane and cyclopentane rings, which can be relevant to polyolefin applications, are obtained with high yields. Several aspects relative to the mechanism of this cyclocopolymerization reaction, including the high stereoselectivity, are discussed.
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- Authors
- Pragliola, S., Milano, G., Guerra, G., & Longo, P.
- Affiliations
- University of Salerno (IT)
- Corresponding author
- Longo, Pasquale
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-03-15
- Volume
- 124
- Issue
- 14
- Pages
- 3502-3503
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2043510257
- Cited by
- 61
- References
- 21
- Citations by year
- 2026: 1 · 2025: 1 · 2024: 2 · 2023: 2 · 2021: 2 · 2019: 3 · 2018: 3 · 2017: 4 · 2016: 1 · 2015: 3 · 2014: 1 · 2013: 2 · 2012: 1
- FWCI
- 3.93
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Cyclopropane Reaction Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- cyclopropanation, cyclocopolymerization, 1,3-butadiene, trans-selectivity, stereoselectivity, cyclopropane ring, cyclopentane ring, polyolefin synthesis, reaction mechanism
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