Cited by 61Cyclopropane Reaction MechanismsOrganometallic Complex Synthesis and CatalysisAdvanced Polymer Synthesis and Characterization

Stereoselective Cyclopropanation by Cyclocopolymerization of Butadiene

Pragliola, Stefania, Milano, Giuseppe, Guerra, Gaetano, Longo, Pasquale·2002·Journal of the American Chemical Society

Abstract

An unprecedented cyclopropanation by cyclopolymerization reaction is presented. In particular, catalytic copolymerization processes of ethene and butadiene lead with high trans selectivity to a complete cyclocopolymerization of butadiene units. Ethene-based copolymers including cyclopropane and cyclopentane rings, which can be relevant to polyolefin applications, are obtained with high yields. Several aspects relative to the mechanism of this cyclocopolymerization reaction, including the high stereoselectivity, are discussed.

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Crossref · 10.1021/ja017416c

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21 of 21 references verified0 citation errors · 0 not checkable

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Authors
Pragliola, S., Milano, G., Guerra, G., & Longo, P.
Affiliations
University of Salerno (IT)
Corresponding author
Longo, Pasquale
Venue
Journal of the American Chemical Society
Published
2002-03-15
Volume
124
Issue
14
Pages
3502-3503
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2043510257
Cited by
61
References
21
Citations by year
2026: 1 · 2025: 1 · 2024: 2 · 2023: 2 · 2021: 2 · 2019: 3 · 2018: 3 · 2017: 4 · 2016: 1 · 2015: 3 · 2014: 1 · 2013: 2 · 2012: 1
FWCI
3.93
Type
journal article
Language
en
Open access
closed
Locations
  • Journal of the American Chemical Society (publishedVersion)
  • PubMed (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Cyclopropane Reaction Mechanisms
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
cyclopropanation, cyclocopolymerization, 1,3-butadiene, trans-selectivity, stereoselectivity, cyclopropane ring, cyclopentane ring, polyolefin synthesis, reaction mechanism

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