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Cited by 490

The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.

Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis

Bruneau, Christian, Dixneuf, Pierre H.·2006·Angewandte Chemie International Edition

Abstract

The involvement of a catalytic metal vinylidene species was proposed for the first time in 1986 to explain the regioselective formation of vinyl carbamates directly from terminal alkynes, carbon dioxide, and amines. Since this initial report, various metal vinylidenes and allenylidenes, which are key activation intermediates, have proved extremely useful for many alkyne transformations. They have contributed to the rational design of new catalytic reactions. This 20th anniversary is a suitable occasion to present the advancement of organometallic vinylidenes and allenylidenes in catalysis.

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Crossref · 10.1002/anie.200501391

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Metadata

Authors
Bruneau, C., & Dixneuf, P. H.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2006-03-17
Volume
45
Issue
14
Pages
2176-2203
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2162107320
Cited by
490
References
43
FWCI
27.72
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis. https://app.cochat.ai/papers/10.1002/anie.200501391
The paper
Bruneau, C., & Dixneuf, P. H. (2006). Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti‐Markovnikov Additions to Terminal Alkynes and Alkene Metathesis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200501391

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.