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Fluoride‐Selective Host Based on Anion–π Interactions, Ion Pairing, and Hydrogen Bonding: Synthesis and Fluoride‐Ion Sandwich Complex
Abstract
A fluoride sandwich: A cylindrophane macrocycle framed with cyanuric acid rings selectively complexes fluoride ion by a combination of anion–π interactions and ion-pair-reinforced hydrogen bonds. This compound is the first example of a purpose-designed host that exploits anion–π bonding.
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Citations
Cited by
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Salonen, L. M., Ellermann, M., & Diederich, F. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007560 · Cited by 1,539
The Bright Future of Unconventional σ/π‐Hole Interactions
Bauzá, A., Mooibroek, T. J., & Frontera, A. (2015) · ChemPhysChem · doi:10.1002/cphc.201500314 · Cited by 710
Recognition and sensing of fluoride anion
Cametti, M., & Rissanen, K. (2009) · Chemical Communications · doi:10.1039/b902069a · Cited by 654
Fluoride Ion Sensing by an Anion−π Interaction
Guha, S., & Saha, S. (2010) · Journal of the American Chemical Society · doi:10.1021/ja107382x · Cited by 507
Anion Recognition Strategies Based on Combined Noncovalent Interactions
Molina, P., Zapata, F., & Caballero, A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00814 · Cited by 406
Metadata
- Authors
- Mascal, M., Yakovlev, I., Nikitin, E. B., & Fettinger, J. C.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2007-11-16
- Volume
- 46
- Issue
- 46
- Pages
- 8782-8784
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2103892722
- Cited by
- 181
- References
- 0
- FWCI
- 8.22
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mascal, M., Yakovlev, I., Nikitin, E. B., & Fettinger, J. C. (2007). Fluoride‐Selective Host Based on Anion–π Interactions, Ion Pairing, and Hydrogen Bonding: Synthesis and Fluoride‐Ion Sandwich Complex. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200704005
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