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Synthesis of Functional Polymers by Post‐Polymerization Modification
Open accessAbstract
Post‐polymerization modification is based on the direct polymerization or copolymerization of monomers bearing chemoselective handles that are inert towards the polymerization conditions but can be quantitatively converted in a subsequent step into a broad range of other functional groups. The success of this method is based on the excellent conversions achievable under mild conditions, the excellent functional‐group tolerance, and the orthogonality of the post‐polymerization modification reactions. This Review surveys different classes of reactive polymer precursors bearing chemoselective handles and discusses issues related to the preparation of these reactive polymers by direct polymerization of appropriately functionalized monomers as well as the post‐polymerization modification of these precursors into functional polymers.
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PEG- and Peptide-Grafted Aliphatic Polyesters by Click Chemistry
Parrish, B., Breitenkamp, R. B., & Emrick, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050310n · Cited by 579
Riva, R., Schmeits, S., Stoffelbach, F., Jérôme, C., Jérôme, R., & Lecomte, P. (2005) · Chemical Communications · doi:10.1039/b510282k · Cited by 208
The aminolysis of N-hydroxysuccinimide esters. A structure-reactivity study
Cline, G. W., & Hanna, S. B. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00244a035 · Cited by 85
Riva, R., Rieger, J., Jérôme, R., & Lecomte, P. (2006) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.21674 · Cited by 48
Cited by
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
Advances in Biomaterials for Drug Delivery
Fenton, O. S., Olafson, K. N., Pillai, P. S., Mitchell, M. J., & Langer, R. (2018) · Advanced Materials · doi:10.1002/adma.201705328 · Cited by 855
Redox-responsive polymers for drug delivery: from molecular design to applications
Huo, M., Yuan, J., Tao, L., & Wei, Y. (2014) · Polym. Chem. · doi:10.1039/c3py01192e · Cited by 561
Expanding the Scope of RAFT Polymerization: Recent Advances and New Horizons
Hill, M. R., Carmean, R. N., & Sumerlin, B. S. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00342 · Cited by 494
Functional Porous Polymers by Emulsion Templating: Recent Advances
Kimmins, S. D., & Cameron, N. R. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201001330 · Cited by 419
Metadata
- Authors
- Gauthier, M. A., Gibson, M. I., & Klok, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2008-12-18
- Volume
- 48
- Issue
- 1
- Pages
- 48-58
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2144591535
- Cited by
- 944
- References
- 4
- FWCI
- 17.33
- Type
- journal article
- Language
- en
- Open access
- green
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- Gauthier, M. A., Gibson, M. I., & Klok, H. (2009). Synthesis of Functional Polymers by Post‐Polymerization Modification. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.200801951
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