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Formation of Linear Supramolecular Polymers That Is Driven by CH⋅⋅⋅π Interactions in Solution and in the Solid State

Zhang, Zibin, Luo, Yan, Chen, Jianzhuang, Dong, Shengyi, Yu, Yihua, Ma, Zhi, Huang, Feihe·2011·Angewandte Chemie International Edition
DOI 10.1002/anie.201006693
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Abstract

Copillararene convoy: A linear supramolecular polymer can be efficiently constructed in solution with a copillararene monomer (see picture). Single-crystal X-ray analysis and NMR spectroscopy revealed that aggregation was enthalpically driven by quadruple CH⋅⋅⋅π interactions between the octyl tail (blue) and the aromatic cavity (red).

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Metadata

Authors
Zhang, Z., Luo, Y., Chen, J., Dong, S., Yu, Y., Ma, Z., & Huang, F.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2011-01-05
Volume
50
Issue
6
Pages
1397-1401
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
DOI
10.1002/anie.201006693
OpenAlex
W2127664681
Cited by
720
References
0
FWCI
39.65
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Formation of Linear Supramolecular Polymers That Is Driven by CH⋅⋅⋅π Interactions in Solution and in the Solid State. https://app.cochat.ai/papers/10.1002/anie.201006693
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Zhang, Z., Luo, Y., Chen, J., Dong, S., Yu, Y., Ma, Z., & Huang, F. (2011). Formation of Linear Supramolecular Polymers That Is Driven by CH⋅⋅⋅π Interactions in Solution and in the Solid State. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201006693

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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.