Graphene‐Supported Hemin as a Highly Active Biomimetic Oxidation Catalyst
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Well supported: stable hemin-graphene conjugates formed by immobilization of monomeric hemin on graphene, showed excellent catalytic activity, more than 10 times better than that of the recently developed hemin-hydrogel system and 100 times better than that of unsupported hemin. The catalysts also showed excellent binding affinities and catalytic efficiencies approaching that of natural enzymes.
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Various carbonaceous materials (graphene, black carbon, and biochar) can act as electron transfer mediators in biotic redox behaviour.
“various carbonaceous materials (graphene, black carbon, and biochar, etc.) could act as electron transfer mediators in biotic redox behaviour.[168][169][170]”
From Sustainable remediation with an electroactive biochar system: mechanisms and perspectives (2020) · cites this paper as [170]
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- Authors
- Xue, T., Jiang, S., Qu, Y., Su, Q., Cheng, R., Dubin, S., Chiu, C., Kaner, R., Huang, Y., & Duan, X.
- Affiliations
- University of California, Los Angeles (US)
- California NanoSystems Institute (US)
- Corresponding author
- Huang, Yu
- Duan, Xiangfeng
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-02-24
- Volume
- 51
- Issue
- 16
- Pages
- 3822-3825
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- PMC
- PMC4249660
- OpenAlex
- W2144253455
- Cited by
- 365
- References
- 42
- Citations by year
- 2026: 6 · 2025: 13 · 2024: 8 · 2023: 12 · 2022: 19 · 2021: 29 · 2020: 30 · 2019: 29 · 2018: 40 · 2017: 38 · 2016: 29 · 2015: 30 · 2014: 34 · 2013: 38 · 2012: 10
- FWCI
- 14.31
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- PubMed Central (acceptedVersion)
- Funders
- National Institutes of Health (1dp2od004342-01, 1dp2od007279-01)
- Topics
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Molecular Biology › Enzyme Catalysis and Immobilization
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Catalyzed Oxygenation Mechanisms
- Physical Sciences › Materials Science › Materials Chemistry › Advanced Nanomaterials in Catalysis
- Keywords
- hemin, graphene, supported metalloporphyrins, enzyme mimics, catalytic efficiency, binding affinity
- MeSH terms
- Catalysis, Graphite, Hemin, Kinetics, Oxidation-Reduction, Oxides, Hydrogel, Polyethylene Glycol Dimethacrylate, Biomimetic Materials
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