Anisotropy Spectra of Amino Acids
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Light on chirality: To predict the enantiomeric enrichment that can be induced into racemic organic molecules with the help of circularly polarized light, the anisotropy factor g is essential. Anisotropy spectra g=f(λ) recorded for proteinaceous amino acids provide crucial information on the transfer of chirality from light to matter.
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Asymmetric photolysis of racemates can induce enantiomeric excess approximated by eqn (2) when anisotropies are close to zero.
“In the common case of two competitive pseudo-first order photolytic reactions with unequal rate constants, k S and k R , for the (S) and (R) enantiomers, respectively, and if the anisotropies are close to zero, the enantiomeric excess induced by asymmetric photolysis can be approximated as eqn (2): 188”
From Possible chemical and physical scenarios towards biological homochirality (2022) · cites this paper as [188]
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- Authors
- Meinert, C., Bredehöft, J. H., Filippi, J., Baraud, Y., Nahon, L., Wien, F., Jones, N. C., Hoffmann, S. V., & Meierhenrich, U. J.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- University of Bremen (DE)
- Synchrotron SOLEIL (FR)
- Aarhus University (DK)
- Corresponding author
- Meierhenrich, Uwe J.
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2012-03-21
- Volume
- 51
- Issue
- 18
- Pages
- 4484-4487
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2097321034
- Cited by
- 64
- References
- 46
- Citations by year
- 2025: 1 · 2024: 5 · 2023: 6 · 2022: 4 · 2021: 5 · 2020: 8 · 2019: 4 · 2018: 5 · 2017: 1 · 2016: 6 · 2015: 2 · 2014: 12 · 2013: 4 · 2012: 1
- FWCI
- 2.69
- Type
- journal article
- Language
- en
- Open access
- green
- zenodo.org
- Licence
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Zenodo (CERN European Organization for Nuclear Research) (submittedVersion, other-oa)
- Funders
- Agence Nationale de la Recherche (ANR-07-BLAN-0293)
- Topics
- Physical Sciences › Chemistry › Spectroscopy › Molecular spectroscopy and chirality
- Physical Sciences › Materials Science › Materials Chemistry › Photochromic and Fluorescence Chemistry
- Physical Sciences › Chemistry › Spectroscopy › Analytical Chemistry and Chromatography
- Keywords
- anisotropy parameter, circularly polarized light, amino acids, chirality transfer, enantiomeric enrichment, circular dichroism
- MeSH terms
- Amino Acids, Stereoisomerism, Anisotropy
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