Cited by 941CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingElectrocatalysts for Energy Conversion

The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.

Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

Calle‐Vallejo, Federico, Koper, Marc T. M.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201301470

Open this paper in CoChat — free account

Abstract

CO-products: DFT calculations are used to construct a mechanism for the electrochemical reduction of CO on Cu(100) that agrees with the experimental observations (see picture) of pH independence in the formation of C2 species. The rate-determining step is an electron-transfer-mediated CO dimerization. Ethylene, acetaldehyde, and ethanol are formed through a common pathway, and adsorbed ethylene oxide is one of the reaction intermediates.

Integrity signals

Registry

Crossref · 10.1002/anie.201301470

Cites

31 of 31 references verified0 citation errors · 0 not checkable

Statistics

Recomputing p-values needs the paper’s full text.

Claims the paper makes

This paper’s full text isn’t openly available, so its claims and self-check weren’t run. The registry and citation checks still apply.

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
A grid-based Bader analysis algorithm without lattice bias
Tang, W., Sanville, E., & Henkelman, G. (2009) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/21/8/084204 · Cited by 7,595
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citation
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Electrolysis of water on (oxidized) metal surfaces
Rossmeisl, J., Logadóttir, Á., & Nørskov, J. K. (2005) · Chemical Physics · doi:10.1016/j.chemphys.2005.05.038 · Cited by 2,044
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482

Flagged first, then by citations

Show all 31 references

Research works printed but not linked: 1

Wade L. G., 2006, Organic Chemistry

Sorted by citations

Items 501–600 of 941

Understanding the restructuring and degradation of oxide-derived copper during electrochemical CO2 reduction
Zhong, D., Cheng, D., Fang, Q., Liu, Y., Li, J., & Zhao, Q. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.143907 · Cited by 35
Pulsed Electrolysis Promotes CO 2 Reduction to Ethanol on Heterostructured Cu 2 O/Ag Catalysts
Wu, X., Li, X., Lv, J., Lv, X., Wu, A., Qi, Z., & Wu, H. B. (2023) · Small · doi:10.1002/smll.202307637 · Cited by 37
Covalent Elaboration of Confined Surfaces Steers C─C Coupling Pathway for Selective Electrochemical CO 2 Reduction at Ampere‐Level
Li, S., Sun, M., Zhang, K., Cai, X. L., Chen, Y., Yang, C., Yang, Z., Tang, X., Huang, B., & Yang, S. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202508366 · Cited by 37
Surface structure and composition effects on electrochemical reduction of carbon dioxide
Zhu, S., & Shao, M. (2015) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-015-2884-x · Cited by 37
Toward Commercial Carbon Dioxide Electrolysis
Ganji, P., Borse, R. A., Xie, J., Mohamed, A. G. A., & Wang, Y. (2020) · Advanced Sustainable Systems · doi:10.1002/adsu.202000096 · Cited by 37
Photo-driven Fischer–Tropsch synthesis
Wu, H.-K., Zhang, F., Li, J., Tang, Z., & Xu, Y. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta09097b · Cited by 38
Spatial-confinement induced electroreduction of CO and CO 2 to diols on densely-arrayed Cu nanopyramids
Chen, L., Tang, C., Davey, K. R., Zheng, Y., Jiao, Y., & Qiao, S. (2021) · Chemical Science · doi:10.1039/d1sc01694f · Cited by 36
Photocatalytic and Photoelectrochemical Carbon Dioxide Reductions toward Value-Added Multicarbon Products
Lu, H., Wang, Z., & Wang, L. (2021) · ACS ES&T Engineering · doi:10.1021/acsestengg.1c00336 · Cited by 37
Metal-organic framework-based single-atom catalysts for efficient electrocatalytic CO2 reduction reactions
Ye, J., Yan, J., Peng, Y., Li, F., & Sun, J. G. (2022) · Catalysis Today · doi:10.1016/j.cattod.2022.09.005 · Cited by 38
Organic molecules involved in Cu-based electrocatalysts for selective CO2 reduction to C2+ products
Chen, P., Wu, Y., Rufford, T. E., Wang, L., Wang, G., & Wang, Z. (2022) · Materials Today Chemistry · doi:10.1016/j.mtchem.2022.101328 · Cited by 37
Recent advances in the regulation of the coordination structures and environment of single-atom catalysts for carbon dioxide reduction reaction
Zhan, Q., Shuai, T., Xu, H., Zhang, Z., & Li, G. (2023) · Journal of Materials Chemistry A · doi:10.1039/d2ta09987j · Cited by 37
Guiding catalytic CO 2 reduction to ethanol with copper grain boundaries
Cheng, D., Zhang, G., Li, L., Shi, X., Zhen, S., Zhao, Z., & Gong, J. (2023) · Chemical Science · doi:10.1039/d3sc02647g · Cited by 38
Solvent Effect on Electrochemical CO2 Reduction Reaction on Nanostructured Copper Electrodes
Deacon-Price, C., da Silva, A. H. M., Santana, C. S., Koper, M. T. M., & Garcia, A. C. (2023) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.3c03257 · Cited by 36
Self-citation
Advances in the understanding of selective CO2 reduction catalysis
Lu, R., Liu, Y., & Wang, Z. (2024) · EcoEnergy · doi:10.1002/ece2.67 · Cited by 37
A computational exploration of CO 2 reduction via CO dimerization on mixed-valence copper oxide surface
Chang, C., Li, E. Y., & Tsai, M. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c8cp00592c · Cited by 37
CuAg bimetallic catalysts derived from an Ag-anchored Cu-based metal–organic framework for CO2 electroreduction to ethanol
Su, W., Guo, W., & Fan, Y. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.147204 · Cited by 35
Progress in Cu‐Based Catalyst Design for Sustained Electrocatalytic CO 2 to C 2+ Conversion
Li, D., Liu, J., Wang, B., Huang, C., & Chu, P. K.-H. (2025) · Advanced Science · doi:10.1002/advs.202416597 · Cited by 39
A DFT study of CO2 electrochemical reduction on Pb(211) and Sn(112)
Cui, C., Wang, H., Zhu, X., Han, J., & Ge, Q. (2015) · Science China Chemistry · doi:10.1007/s11426-015-5323-z · Cited by 35
Impact of the AuAg NPs Composition on Their Structure and Properties: A Theoretical and Experimental Investigation
Gomes, J. F., Garcia, A. C., Pires, C., Ferreira, E. B., Albuquerque, R. Q., Tremiliosi‐Filho, G., & Gasparotto, L. H. S. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp509437a · Cited by 35
Isotope Effects in Plasmonic Photosynthesis
Yu, S., & Jain, P. K. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202011805 · Cited by 35
Steric effect induces CO electroreduction to CH 4 on Cu–Au alloys
Guan, A., Wang, Q., Ji, Y., Li, S., Yang, C., Qian, L., Zhang, L., Wu, L., & Zheng, G. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta06162c · Cited by 35
Role of the Adsorbed Oxygen Species in the Selective Electrochemical Reduction of CO2 to Alcohols and Carbonyls on Copper Electrodes
Duff, C. S. L., Lawrence, M. J., & Rodríguez, P. (2017) · Angewandte Chemie · doi:10.1002/ange.201706463 · Cited by 35
Mechanistic Understanding of CO2 Electroreduction on Cu2O
Qi, L., Liu, S., Gao, W., & Jiang, Q. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b11842 · Cited by 35
Product Distribution Control Guided by a Microkinetic Analysis for CO Reduction at High-Flux Electrocatalysis Using Gas-Diffusion Cu Electrodes
Lü, X., Shinagawa, T., & Takanabe, K. (2023) · ACS Catalysis · doi:10.1021/acscatal.2c04802 · Cited by 36
Copper-based catalysts for CO2 electroreduction to C2/2+ products: Advance and perspective
Wang, F., Lu, Z., Guo, H., Hao, G., Jiang, W., & Liu, G. (2024) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2024.215962 · Cited by 35
Facet-dependent electrocatalysis in the HCOOH synthesis from CO2 reduction on Cu catalyst: a density functional theory study
Jo, D. Y., Ham, H. C., & Lee, K. (2020) · Applied Surface Science · doi:10.1016/j.apsusc.2020.146857 · Cited by 34
Theoretical Insights into Potential-Dependent C–C Bond Formation Mechanisms during CO 2 Electroreduction into C 2 Products on Cu(100) at Simulated Electrochemical Interfaces
Ou, L., He, Z., Yang, H., & Chen, Y. (2021) · ACS Omega · doi:10.1021/acsomega.1c01062 · Cited by 31
Advanced in-situ electrochemical scanning probe microscopies in electrocatalysis
Liu, D., Zhang, B., Zhao, G., Chen, J., Pan, H., & Sun, W. (2023) · CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · doi:10.1016/s1872-2067(23)64396-7 · Cited by 35
Reactivity of Copper Electrodes towards Functional Groups and Small Molecules in the Context of CO2 Electro-Reductions
Schmid, B., Reller, C., Neubauer, S., Fleischer, M., Dorta, R., & Schmid, G. (2017) · Catalysts · doi:10.3390/catal7050161 · Cited by 33
Ethylene Selectivity in CO Electroreduction when using Cu Oxides: An In Situ ATR‐SEIRAS Study
Lee, S., & Lee, J. (2017) · ChemElectroChem · doi:10.1002/celc.201700892 · Cited by 33
Modeling of gas bubble-induced mass transport in the electrochemical reduction of carbon dioxide on nanostructured electrodes
Sacco, A., Zeng, J., Bejtka, K., & Chiodoni, A. M. (2019) · Journal of Catalysis · doi:10.1016/j.jcat.2019.02.016 · Cited by 33
Impact of Forced Convection on Spectroscopic Observations of the Electrochemical CO Reduction Reaction
Malkani, A. S., Li, J., Anibal, J., Lu, Q., & Xu, B. (2019) · ACS Catalysis · doi:10.1021/acscatal.9b03581 · Cited by 33
Bifunctional Nickel–Nitrogen-Doped-Carbon-Supported Copper Electrocatalyst for CO2Reduction
Choukroun, D., Daems, N., Kenis, T., Everbroeck, T. V., Hereijgers, J., Altantzis, T., Bals, S., Cool, P., & Breugelmans, T. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b08931 · Cited by 34
Visible/infrared light-driven high-efficiency CO 2 conversion into ethane based on a B–Co synergistic catalyst
Li, L., Guo, H., Yao, G., Hu, C., Liu, C., Tian, Z., Li, B., Zhang, Q., & Chen, L. (2020) · Journal of Materials Chemistry A · doi:10.1039/d0ta05821a · Cited by 33
Optimizing CO Coverage on Rough Copper Electrodes: Effect of the Partial Pressure of CO and Electrolyte Anions (pH) on Selectivity toward Ethylene
Moradzaman, M., & Mul, G. (2021) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c10792 · Cited by 33
On the shifting peak of volcano plots for oxygen reduction and evolution
Sargeant, E., Illas, F., Rodríguez, P., & Calle‐Vallejo, F. (2022) · Electrochimica Acta · doi:10.1016/j.electacta.2022.140799 · Cited by 33
Self-citation
Towards understanding of CO 2 electroreduction to C 2+ products on copper‐based catalysts
Liu, T., Sang, J., Li, H., Wei, P., Zang, Y., & Wang, G. (2022) · Battery energy · doi:10.1002/bte2.20220012 · Cited by 34
The Influence of Mesoscopic Surface Structure on the Electrocatalytic Selectivity of CO 2 Reduction with UHV-Prepared Cu(111) Single Crystals
Nguyen, K. C., Bruce, J. P., Yoon, A., Navarro, J. J., Scholten, F., Landwehr, F., Rettenmaier, C., Heyde, M., & Cuenya, B. R. (2024) · ACS Energy Letters · doi:10.1021/acsenergylett.3c02693 · Cited by 32
New Mechanistic Insights into CO 2 /CO Electroreduction to Acetate by Combining Computations and Experiments
Bai, X., He, M. S., Xu, Y., Xu, B., Lu, Q., Wang, J., & Ling, C. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c05825 · Cited by 32
Rational Modulation of Interface Microenvironment and Design of the Flow Electrolyzer for CO x Electroreduction to Alcohol
Chen, J., Peng, X., Li, Z., Yang, B., Zhang, Q., Lü, J., Lei, L., & Hou, Y. (2024) · Advanced Materials · doi:10.1002/adma.202409106 · Cited by 34
Seriatim ECSTM-ECPMIRS of the adsorption of carbon monoxide on Cu(100) in alkaline solution at CO2-reduction potentials
Baricuatro, J. H., Kim, Y.-G., Korzeniewski, C. L., & Soriaga, M. P. (2018) · Electrochemistry Communications · doi:10.1016/j.elecom.2018.04.016 · Cited by 33
Pseudo-copper Ni-Zn alloy catalysts for carbon dioxide reduction to C2 products
Zhang, X., Liu, K., Fu, J., Li, H., Pan, H., Hu, J., & Liu, M. (2021) · Frontiers of Physics · doi:10.1007/s11467-021-1079-4 · Cited by 34
Recent Progress in Electrocatalytic Conversion of CO2 to Valuable C2 Products
Yan, Z., Liu, W., Liu, X., Shen, Z., Li, X., & Cao, D. (2023) · Advanced Materials Interfaces · doi:10.1002/admi.202300186 · Cited by 33
Size effects of supported Cu-based catalysts for the electrocatalytic CO 2 reduction reaction
Su, X., Wang, C., Zhao, F., Wei, T., Zhao, D., & Zhang, J. (2023) · Journal of Materials Chemistry A · doi:10.1039/d3ta04929a · Cited by 30
Electrochemical CO 2 Reduction: A Review toward Sustainable Energy Conversion and Storage
Ullah, N., Shah, S. S., Suliman, M. H., Ismail, F. M., Kaci, S., Amin, N. A. S., & Usman, M. (2025) · Energy & Fuels · doi:10.1021/acs.energyfuels.5c03761 · Cited by 36
Enhanced CO2 electroreduction to multi-carbon products in strong acid induced by surface-adsorbed iodide ions
Ding, X., Pan, B., Fan, B., Yu, Q., Xu, J., Yan, Y., Luo, Y., Wang, L., & Li, Y. (2025) · Nature Energy · doi:10.1038/s41560-025-01924-4 · Cited by 40
CdS‐Enhanced Ethanol Selectivity in Electrocatalytic CO 2 Reduction at Sulfide‐Derived Cu−Cd
Mosali, V. S. S., Zhang, X., Liang, Y., Li, L., Puxty, G., Horne, M. D., Brajter‐Toth, A., Bond, A. M., & Zhang, J. (2021) · ChemSusChem · doi:10.1002/cssc.202100903 · Cited by 32
Tuning CO binding strength via engineering the copper/borophene interface for highly efficient conversion of CO into ethanol
He, T., Tang, C., Santiago, A. R. P., Luque, R., Pan, H., & Du, A. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta02355a · Cited by 31
Electrocatalytic CO 2 reduction reaction on dual-metal- and nitrogen-doped graphene: coordination environment effect of active sites
He, P., Feng, H., Wang, S., Ding, H., Liang, Y., Ling, M., & Zhang, X. (2022) · Materials Advances · doi:10.1039/d2ma00192f · Cited by 31
Hydroxide Is Not a Promoter of C2+ Product Formation in the Electrochemical Reduction of CO on Copper
Li, J., Wu, D., Malkani, A. S., Chang, X., Cheng, M., Xu, B., & Lu, Q. (2019) · Angewandte Chemie · doi:10.1002/ange.201912412 · Cited by 31
Carbon Catalysts Empowering Sustainable Chemical Synthesis via Electrochemical CO 2 Conversion and Two‐Electron Oxygen Reduction Reaction
Zhao, Y., Raj, J., Xu, X. M., Jiang, J., Wu, J., & Fan, M. (2024) · Small · doi:10.1002/smll.202311163 · Cited by 32
Three-dimension porous Zn-Cu alloy: An inexpensive electrocatalyst for highly selective CO2 reduction to CO in non-aqueous electrolyte
Zhang, Z., Li, S., Rao, Y., Liu, Y., Yan, W., & Xu, H. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.147376 · Cited by 30
Advancing C–C coupling of the electrocatalytic CO 2 reduction reaction for C 2+ products
Liang, G., Yang, S., Wu, C., Liu, Y., Zhao, Y., Huang, L. W., Zhang, S., Dou, S. X., Du, H., Cui, D., et al. (2025) · Journal of Materials Chemistry A · doi:10.1039/d4ta09210d · Cited by 29
Insight into CO Activation over Cu(100) under Electrochemical Conditions
Sheng, T., Wang, D., Lin, W., Hu, P., & Sun, S. (2016) · Electrochimica Acta · doi:10.1016/j.electacta.2016.01.037 · Cited by 30
Improved Prediction of Nanoalloy Structures by the Explicit Inclusion of Adsorbates in Cluster Expansions
Li, C., Raciti, D., Pu, T., Cao, L., He, C., Wang, C., & Mueller, T. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b03868 · Cited by 33
Strategies for overcoming challenges in selective electrochemical CO2 conversion to ethanol
Wang, Z., Li, Y., Ma, Z., Wang, D., & Ren, X. (2024) · iScience · doi:10.1016/j.isci.2024.110437 · Cited by 30
Reaction-Driven Varieties of Active Sites on Cu(100) in Electrochemical CO2 Reduction Reaction
Zhang, S., Tang, Q., Zhu, B., & Gao, Y. (2025) · ACS Catalysis · doi:10.1021/acscatal.4c07168 · Cited by 31
Clean and Reproducible Voltammetry of Copper Single Crystals with Prominent Facet-Specific Features Using Induction Annealing
Raaijman, S. J., Arulmozhi, N., da Silva, A. H. M., & Koper, M. T. M. (2021) · Journal of The Electrochemical Society · doi:10.1149/1945-7111/ac24b9 · Cited by 29
Self-citation
Sulfurization-derived Cu0–Cu+ sites for electrochemical CO2 reduction to ethanol
Dou, T., Du, J., He, J., Wang, Y., Zhao, X., Zhang, F., & Lei, X. (2022) · Journal of Power Sources · doi:10.1016/j.jpowsour.2022.231393 · Cited by 29
Planar defect-driven electrocatalysis of CO 2 -to-C 2 H 4 conversion
Li, Z., Fang, Y., Zhang, J., Zhang, T., Jiménez, J. D., Senanayake, S. D., Shanov, V. N., Yang, S., & Wu, J. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta02565a · Cited by 30
Copper-based bimetallic electrocatalysts for CO2 reduction: From mechanism understandings to product regulations
Yang, H., Chuai, H., Meng, Q., Wang, M., Zhang, S., & Ma, X. (2022) · Materials Reports Energy · doi:10.1016/j.matre.2022.100174 · Cited by 29
Rational design of bimetallic catalysts for electrochemical CO2 reduction reaction: A review
Li, M., & Zhang, J. (2023) · Science China Chemistry · doi:10.1007/s11426-023-1565-5 · Cited by 28
Nanocavity enriched CuPd alloy with high selectivity for CO 2 electroreduction toward C 2 H 4
Zhang, Z., Wang, H., Zhang, F.-F., Li, J., Hu, X.-Z., Yan, S.-W., Bai, Y., Zhang, X., Shen, G., Yin, P., et al. (2024) · Rare Metals · doi:10.1007/s12598-023-02527-2 · Cited by 28
Improving the Accuracy of Modelling CO2 Electroreduction on Copper Using Many‐Body Perturbation Theory
Wei, Z., & Sautet, P. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202210060 · Cited by 27
Ru Single Atom Dispersed Cu Nanoparticle with Dual Sites Enables Outstanding Photocatalytic CO 2 Reduction
Liu, L., Hu, J., Sheng, Y., Akhoundzadeh, H., Tu, W., Siow, W. J. S., Ong, J. H., Huang, H., & Xu, R. Q. (2024) · ACS Nano · doi:10.1021/acsnano.4c08303 · Cited by 27
Electrolyte Effect on Electrochemical CO2 Reduction to Multicarbon Products
Zhong, X., Peng, H., Xia, C., & Liu, X. (2024) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.4c00021 · Cited by 27
Recent advances in single crystal and facet dependency of copper electrodes on electrochemical CO2 reduction
Qiao, Y., & Seger, B. J. (2024) · Current Opinion in Chemical Engineering · doi:10.1016/j.coche.2023.100999 · Cited by 25
Metal–Organic Frameworks for Electrocatalytic CO2 Reduction: Developments and Prospects
Patel, S., McKelvey, K., & Liu, L. (2024) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c01137 · Cited by 27
AI for Complex Catalytic Systems: High-Entropy Alloys in Electrocatalytic Acetylene Semihydrogenation
Tan, Z. W., Li, X., Bai, R., Guo, C., Han, X. Y., Shi, Q., Zhang, J., & Li, H. (2025) · ACS Catalysis · doi:10.1021/acscatal.5c04236 · Cited by 25
Universal Principle to Describe Reactivity and Selectivity of CO 2 Electroreduction on Transition Metals and Single-Atom Catalysts
Guan, X., Zhao, C., Liu, X., Liu, S., Gao, W., & Jiang, Q. (2020) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c08745 · Cited by 26
Theoretical insights into mechanisms of electrochemical reduction of CO2 to ethylene catalyzed by Pd3Au
Zheng, M., Zhou, X., Zhou, Y., & Li, M. (2021) · Applied Surface Science · doi:10.1016/j.apsusc.2021.151474 · Cited by 25
C 2 product formation in the CO 2 electroreduction on boron-doped graphene anchored copper clusters
Barhács, B., Janssens, E., & Höltzl, T. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp01316a · Cited by 26
Grazing incidence X-Ray diffraction: identifying the dominant facet in copper foams that electrocatalyze the reduction of carbon dioxide to formate
Ahn, S. T., Sen, S., & Palmore, G. T. R. (2022) · Nanoscale · doi:10.1039/d2nr03212k · Cited by 27
Hydrocarbon adsorption in an aqueous environment: A computational study of alkyls on Cu(111)
Montemore, M. M., Andreussi, O., & Medlin, J. W. (2016) · The Journal of Chemical Physics · doi:10.1063/1.4961027 · Cited by 25
Recent advances in nanoscale engineering of Pd-based electrocatalysts for selective CO2 electroreduction to formic acid/formate
Sun, S., Mao, Y., Liu, F., Zhang, S., Sun, Y., Gao, Q., & Liu, X. (2024) · Energy Materials · doi:10.20517/energymater.2023.88 · Cited by 25
Enhanced CO2 electroreduction to ethylene on Cu nanocube coated with nitrogen-doped carbon shell in-situ electro-derived from metal-organic framework
Zhang, N., & Zhang, Y. (2024) · Chemical Engineering Journal · doi:10.1016/j.cej.2024.156694 · Cited by 25
Enhancing C 2+ Product Faradaic Efficiency in CO 2 Reduction Using Fluorine-Stabilized Superhydrophobic Copper (δ+)
Chawla, G., Dutta, N., Kediya, S., Bagchi, D., Pulparambil, A., Rankin, A. G. M., Das, S., Chakraborty, S., Reddy, G. N. M., & Peter, S. C. (2025) · Journal of the American Chemical Society · doi:10.1021/jacs.5c10233 · Cited by 25
Rise of nano effects in electrode during electrocatalytic CO 2 conversion
Yang, K. D., Lee, C. W., Jang, J. H., 하탁래, & Nam, K. T. (2017) · Nanotechnology · doi:10.1088/1361-6528/aa7b0b · Cited by 25
Cu/LaF3 Interfaces Boost Electrocatalytic CO-to-Acetate Conversion
Zhao, Y., Li, Y., Chen, J., Sun, B., Fan, L., Chen, J., Xiao, Y., Yang, H., Wang, D., Chen, J., et al. (2024) · ACS Catalysis · doi:10.1021/acscatal.3c06014 · Cited by 24
Concentrated C2+ Alcohol Production Enabled by Post-Intermediate Modulation and Augmented CO Adsorption in CO Electrolysis
Zhou, G., Li, B., Cheng, G., Breckner, C. J., Dean, D. P., Yang, M., Yao, N., Miller, J. T., Klok, J. B. M., Tsesmetzis, N., et al. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.4c10629 · Cited by 24
Recent advances in electrocatalytic conversion of CO2-to-ethylene: From reaction mechanisms to tuning strategies
Zhang, N., & Zhang, Y. (2024) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2024.124822 · Cited by 23
P and Cu Dual Sites on Graphitic Carbon Nitride for Photocatalytic CO2 Reduction to Hydrocarbon Fuels with High C2H6 Evolution
Wang, G., Chen, Z., Wang, T., Wang, D. S., & Mao, J. (2022) · Angewandte Chemie · doi:10.1002/ange.202210789 · Cited by 24
Elucidating Reaction Pathways of the CO2 Electroreduction via Tailorable Tortuosities and Oxidation States of Cu Nanostructures
Liu, G., Adesina, P., Nasiri, N., Wang, H., Sheng, Y., Wu, S., Kraft, M., Lapkin, A. A., Ager, J. W., & Xu, R. Q. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202204993 · Cited by 24
Current state of copper-based bimetallic materials for electrochemical CO 2 reduction: a review
Zoubir, O., Atourki, L., Ahsaine, H. A., & BaQais, A. (2022) · RSC Advances · doi:10.1039/d2ra05385c · Cited by 25
Loading metal nanoparticles on the CoAl-LDH/CGCNN S-scheme heterojunction for efficient photocatalytic CO2 reduction under visible light
Li, C., Guo, R., Zhang, Z.-R., Wu, T., Yue, C.-M., & Pan, W. (2023) · Separation and Purification Technology · doi:10.1016/j.seppur.2023.124266 · Cited by 24
Efficient electrochemical CO2 reduction to C2+ hydrocarbons on Zn-doped Cu films
Yang, Y., Fu, H., Xiao, C., Du, X., & Song, Z. (2023) · Applied Surface Science · doi:10.1016/j.apsusc.2023.158866 · Cited by 25
Why do RuO 2 electrodes catalyze electrochemical CO 2 reduction to methanol rather than methane or perhaps neither of those?
Tayyebi, E., Hussain, J., & Skúlason, E. (2020) · Chemical Science · doi:10.1039/d0sc01882a · Cited by 25
Quantitative Analysis and Manipulation of Alkali Metal Cations at the Cathode Surface in Membrane Electrode Assembly Electrolyzers for CO 2 Reduction Reactions
Kato, S., Ito, S., Nakahata, S., Kurihara, R., Harada, T., Nakanishi, S., & Kamiya, K. (2024) · ChemSusChem · doi:10.1002/cssc.202401013 · Cited by 23
Biodiesel production by the electrocatalytic process: a review
Thangaraj, B., & Solomon, P. R. (2021) · Clean Energy · doi:10.1093/ce/zkaa026 · Cited by 22
Electrochemical conversion of CO2 in non‐conventional electrolytes: Recent achievements and future challenges
Sargeant, E., & Rodríguez, P. (2022) · Electrochemical Science Advances · doi:10.1002/elsa.202100178 · Cited by 23
Tandem engineering for CO2 electrolysis toward multicarbon products
Yang, T., Kuang, M., & Yang, J. (2023) · Nano Research · doi:10.1007/s12274-023-5656-4 · Cited by 24
Influence of Copper Sites with Different Coordination on the Adsorption and Electroreduction of CO2 and CO
You, F., Xi, S., Ho, J. J. Y., Calle‐Vallejo, F., & Yeo, B. S. (2023) · ACS Catalysis · doi:10.1021/acscatal.3c03197 · Cited by 24
Self-citation
Theoretical search for novel Au or Ag bimetallic alloys capable of transforming CO 2 into hydrocarbons
Wu, N. F., Xiao, L., & Zhuang, L. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta07929g · Cited by 23
Recent progress, developing strategies, theoretical insights, and perspectives towards high-performance copper single atom electrocatalysts
Wang, J., Xu, R., Li, Y., Li, Y., Yang, M., Yang, G., Zhao, Y., & Gao, F. (2021) · Materials Today Energy · doi:10.1016/j.mtener.2021.100761 · Cited by 22
Development of catalysts and reactor designs for CO2 electroreduction towards C2+ products
Ma, J., & Kim, S. Y. (2025) · Energy Materials · doi:10.20517/energymater.2024.237 · Cited by 22
Electrochemical Reduction of CO 2 to Multicarbon Products: A Review on Catalysts and System Optimization toward Industrialization
Zheng, H., Shi, K., Dong, H., Yang, Y., Yin, P., Shen, B., & Wang, J. (2025) · Energy & Fuels · doi:10.1021/acs.energyfuels.5c00893 · Cited by 24
Recent advances in Cu-based catalysts for electrocatalytic CO2 reduction reaction to C2+ products: Oxidation state of metal centers, crystal facet and micro morphology of catalyst structure
Niu, Y., Zhang, J., Tang, X., Yi, H., Zhao, S., Zhou, Y., & Gao, F. (2025) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2025.216763 · Cited by 22
Electrocatalytic Carbon Dioxide Reduction to Ethylene over Copper‐based Catalytic Systems
Yang, Y., Tan, Z., & Zhang, J. (2022) · Chemistry - An Asian Journal · doi:10.1002/asia.202200893 · Cited by 24
Multifunctional Au/Hydroxide Interface toward Enhanced C–C Coupling for Solar-Driven CO2 Reduction into C2H6
Lü, L., Cheng, Y. H., Liang, Z., Yan, S., Qiao, G., & Zou, Z. (2023) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.2c04419 · Cited by 22
Electrocatalytic Reduction of CO2 to Value‐Added Chemicals via C–C/N Coupling
Liu, J., Zhang, X., Yang, R., Yang, Y. A., & Wang, X. (2023) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202200192 · Cited by 21

Authors: Calle‐Vallejo, F., & Koper, M. T. M.
Affiliations: Leiden University (NL)
Corresponding author: Koper, Marc T. M.
ORCID: Calle‐Vallejo, Federico
Koper, Marc T. M.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-06-03
Volume: 52
Issue: 28
Pages: 7282-7285
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201301470
OpenAlex: W2158532118
Cited by: 941
References: 31
Citations by year: 2026: 59 · 2025: 106 · 2024: 106 · 2023: 102 · 2022: 104 · 2021: 95 · 2020: 92 · 2019: 80 · 2018: 60 · 2017: 49 · 2016: 43 · 2015: 30 · 2014: 12 · 2013: 3
FWCI: 10.65
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: CO dimerization, C2+ products, reaction mechanism, rate-determining step, electron transfer, ethylene, acetaldehyde, ethanol, pH independence, adsorbed intermediates

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review

Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

Abstract

Overview

Integrity signals

Verification

Claims the paper makes

Claims other papers make about this one

Citations

Cites

Cited by

Related

Metadata

Record

About these checks