Cited by 941CO2 Reduction Techniques and CatalystsCatalysts for Methane ReformingElectrocatalysts for Energy Conversion

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Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

Calle‐Vallejo, Federico, Koper, Marc T. M.·2013·Angewandte Chemie International Edition

DOI 10.1002/anie.201301470

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Abstract

CO-products: DFT calculations are used to construct a mechanism for the electrochemical reduction of CO on Cu(100) that agrees with the experimental observations (see picture) of pH independence in the formation of C2 species. The rate-determining step is an electron-transfer-mediated CO dimerization. Ethylene, acetaldehyde, and ethanol are formed through a common pathway, and adsorbed ethylene oxide is one of the reaction intermediates.

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Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell Cathode
Nørskov, J. K., Rossmeisl, J., Logadottir, A., Lindqvist, L., Kitchin, J. R., Bligaard, T., & Jónsson, H. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp047349j · Cited by 13,153
A grid-based Bader analysis algorithm without lattice bias
Tang, W., Sanville, E., & Henkelman, G. (2009) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/21/8/084204 · Cited by 7,595
Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces
Man, I. C., Su, H., Calle‐Vallejo, F., Hansen, H. A., Martínez, J. I., Inoglu, N. G., Kitchin, J., Jaramillo, T. F., Nørskov, J. K., & Rossmeisl, J. (2011) · ChemCatChem · doi:10.1002/cctc.201000397 · Cited by 4,769
Self-citation
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Electrolysis of water on (oxidized) metal surfaces
Rossmeisl, J., Logadóttir, Á., & Nørskov, J. K. (2005) · Chemical Physics · doi:10.1016/j.chemphys.2005.05.038 · Cited by 2,044
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. C. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,482

Show all 31 references

Research works printed but not linked: 1

Wade L. G., 2006, Organic Chemistry

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Authors: Calle‐Vallejo, F., & Koper, M. T. M.
Affiliations: Leiden University (NL)
Corresponding author: Koper, Marc T. M.
ORCID: Calle‐Vallejo, Federico
Koper, Marc T. M.
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2013-06-03
Volume: 52
Issue: 28
Pages: 7282-7285
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201301470
OpenAlex: W2158532118
Cited by: 941
References: 31
Citations by year: 2026: 59 · 2025: 106 · 2024: 106 · 2023: 102 · 2022: 104 · 2021: 95 · 2020: 92 · 2019: 80 · 2018: 60 · 2017: 49 · 2016: 43 · 2015: 30 · 2014: 12 · 2013: 3
FWCI: 10.65
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Keywords: CO dimerization, C2+ products, reaction mechanism, rate-determining step, electron transfer, ethylene, acetaldehyde, ethanol, pH independence, adsorbed intermediates

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Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes

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