The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Theoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
Abstract
CO-products: DFT calculations are used to construct a mechanism for the electrochemical reduction of CO on Cu(100) that agrees with the experimental observations (see picture) of pH independence in the formation of C2 species. The rate-determining step is an electron-transfer-mediated CO dimerization. Ethylene, acetaldehyde, and ethanol are formed through a common pathway, and adsorbed ethylene oxide is one of the reaction intermediates.
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“Consequently, early CO dimerization was proposed as a pathway for CO reduction to ethylene (Figure 2, red pathways), ethanol (Figure 2, blue pathways), and acetaldehyde.[55]”
From Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design (2019) · cites this paper as [55]
Citations
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Self-citationHow copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
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Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis
Gawande, M. B., Goswami, A., Felpin, F., Asefa, T., Huang, X., Silva, R., Zou, X., Zbořil, R., & Varma, R. S. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00482 · Cited by 3,000
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
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Self-citationCatalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide
Kortlever, R., Shen, J., Schouten, K. J. P., Calle‐Vallejo, F., & Koper, M. T. M. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b01559 · Cited by 2,217
Self-citationElectroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Metadata
- Authors
- Calle‐Vallejo, F., & Koper, M. T. M.
- Affiliations
- Leiden University (NL)
- Corresponding author
- Koper, Marc T. M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-06-03
- Volume
- 52
- Issue
- 28
- Pages
- 7282-7285
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2158532118
- Cited by
- 941
- References
- 31
- Citations by year
- 2026: 59 · 2025: 106 · 2024: 106 · 2023: 102 · 2022: 104 · 2021: 95 · 2020: 92 · 2019: 80 · 2018: 60 · 2017: 49 · 2016: 43 · 2015: 30 · 2014: 12 · 2013: 3
- FWCI
- 10.65
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Keywords
- CO dimerization, C2+ products, reaction mechanism, rate-determining step, electron transfer, ethylene, acetaldehyde, ethanol, pH independence, adsorbed intermediates
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