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Cited by 427

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Solvent‐Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal–Organic Frameworks

Karagiaridi, Olga, Bury, Wojciech, Mondloch, Joseph E., Hupp, Joseph T., Farha, Omar K.·2014·Angewandte Chemie International Edition

Abstract

Metal‐organic frameworks (MOFs) have gained considerable attention as hybrid materials—in part because of a multitude of potential useful applications, ranging from gas separation to catalysis and light harvesting. Unfortunately, de novo synthesis of MOFs with desirable function–property combinations is not always reliable and may suffer from vagaries such as formation of undesirable topologies, low solubility of precursors, and loss of functionality of the sensitive network components. The recently discovered synthetic approach coined solvent‐assisted linker exchange (SALE) constitutes a simple to implement strategy for circumventing these setbacks; its use has already led to the generation of a variety of MOF materials previously unobtainable by direct synthesis methods. This Review provides a perspective of the achievements in MOF research that have been made possible with SALE and examines the studies that have facilitated the understanding and broadened the scope of use of this invaluable synthetic tool.

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Metadata

Authors
Karagiaridi, O., Bury, W., Mondloch, J. E., Hupp, J. T., & Farha, O. K.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-03-20
Volume
53
Issue
18
Pages
4530-4540
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2090752769
Cited by
427
References
4
FWCI
17.50
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Solvent‐Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal–Organic Frameworks. https://app.cochat.ai/papers/10.1002/anie.201306923
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Karagiaridi, O., Bury, W., Mondloch, J. E., Hupp, J. T., & Farha, O. K. (2014). Solvent‐Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal–Organic Frameworks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201306923

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