The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Ionic‐Liquid–Nanoparticle Hybrid Electrolytes: Applications in Lithium Metal Batteries
Abstract
Development of rechargeable lithium metal battery (LMB) remains a challenge because of uneven lithium deposition during repeated cycles of charge and discharge. Ionic liquids have received intensive scientific interest as electrolytes because of their exceptional thermal and electrochemical stabilities. Ionic liquid and ionic‐liquid–nanoparticle hybrid electrolytes based on 1‐methy‐3‐propylimidazolium (IM) and 1‐methy‐3‐propylpiperidinium (PP) have been synthesized and their ionic conductivity, electrochemical stability, mechanical properties, and ability to promote stable Li electrodeposition investigated. PP‐based electrolytes were found to be more conductive and substantially more efficient in suppressing dendrite formation on cycled lithium anodes; as little as 11 wt % PP‐IL in a PC‐LiTFSI host produces more than a ten‐fold increase in cell lifetime. Both PP‐ and IM‐based nanoparticle hybrid electrolytes provide up to 10 000‐fold improvements in cell lifetime than anticipated based on their mechanical modulus alone. Galvanostatic cycling measurements in Li/Li 4 Ti 5 O 12 half cells using IL–nanoparticle hybrid electrolytes reveal more than 500 cycles of trouble‐free operation and enhanced rate capability.
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Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Design principles for electrolytes and interfaces for stable lithium-metal batteries
Tikekar, M. D., Choudhury, S., Tu, Z., & Archer, L. A. (2016) · Nature Energy · doi:10.1038/nenergy.2016.114 · Cited by 1,765
Self-citationAdvancing Lithium Metal Batteries
Liu, B., Zhang, J.-G., & Xu, W. (2018) · Joule · doi:10.1016/j.joule.2018.03.008 · Cited by 1,647
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes
Lu, Y., Tu, Z., & Archer, L. A. (2014) · Nature Materials · doi:10.1038/nmat4041 · Cited by 1,592
Self-citationThe synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
Li, W., Yao, H., Yan, K., Zheng, G., Liang, Z., Chiang, Y.-M., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8436 · Cited by 1,540
Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
Adams, B. D., Zheng, J., Ren, X., Xu, W., & Zhang, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702097 · Cited by 1,499
Metadata
- Authors
- Lu, Y., Korf, K., Kambe, Y., Tu, Z., & Archer, L. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-11-26
- Volume
- 53
- Issue
- 2
- Pages
- 488-492
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2166608679
- Cited by
- 348
- References
- 2
- FWCI
- 11.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lu, Y., Korf, K., Kambe, Y., Tu, Z., & Archer, L. A. (2014). Ionic‐Liquid–Nanoparticle Hybrid Electrolytes: Applications in Lithium Metal Batteries. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201307137
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