The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper‐Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes
Open accessAbstract
Something radical: An efficient enantioselective oxytrifluoromethylation of alkenes has been developed using a copper catalyst system. Mechanistic studies are consistent with a metal-catalyzed redox radical addition mechanism in which a CO bond is formed by the copper-mediated enantioselective trapping of a prochiral alkyl radical intermediate derived from the initial trifluoromethyl radical addition.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
A “Renaissance” in Radical Trifluoromethylation
Studer, A. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201202624 · Cited by 1,073
Wallentin, C.-J., Nguyen, J. D., Finkbeiner, P., & Stephenson, C. R. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja300798k · Cited by 969
Nguyen, J. D., Tucker, J. W., Konieczynska, M. D., & Stephenson, C. R. J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja108560e · Cited by 772
Yasu, Y., Koike, T., & Akita, M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201205071 · Cited by 551
Free-radical additions to olefins in the presence of redox systems
Minisci, F. (1975) · Accounts of Chemical Research · doi:10.1021/ar50089a004 · Cited by 329
Koller, R., Stanek, K., Stolz, D., Aardoom, R., Niedermann, K., & Togni, A. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200900974 · Cited by 313
Copper‐Catalyzed Trifluoromethylation of Allylsilanes
Shimizu, R., Egami, H., Hamashima, Y., & Sodeoka, M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201201095 · Cited by 215
Muñoz‐Molina, J. M., Belderraín, T. R., & Pérez, P. J. (2011) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201100379 · Cited by 136
Koller, R., Stanek, K., Stolz, D., Aardoom, R., Niedermann, K., & Togni, A. (2009) · Angewandte Chemie · doi:10.1002/ange.200900974 · Cited by 110
Metadata
- Authors
- Zhu, R., & Buchwald, S. L.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2013-10-16
- Volume
- 52
- Issue
- 48
- Pages
- 12655-12658
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2115824676
- Cited by
- 294
- References
- 12
- FWCI
- 17.92
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper‐Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes. https://app.cochat.ai/papers/10.1002/anie.201307790
- The paper
- Zhu, R., & Buchwald, S. L. (2013). Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper‐Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201307790
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.