CO2 Fixation through Hydrogenation by Chemical or Enzymatic Methods
Abstract
Two birds with one stone: The simulaneous fixation of the greenhouse gas carbon dioxide and storage of the alternative fuel hydrogen can be accomplished with the formation of formic acid. In principle, this is now possible either with an enzymatic system based on a newly discovered bacterial hydrogen-dependent carbon dioxide reductase or by using organometallic catalysts at room temperature and ambient pressure.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Various useful reduction products such as CO, HCOOH, carboxylic acids, and cyclic carbonates have been successfully obtained through enzymatic and organometallic conversions.
“Various useful reduction products such as CO, HCOOH, carboxylic acids, and cyclic carbonates have been successfully obtained.330, 331, 332, 333”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [330]
Cites
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193 · see citing works
Hull, J. F., Himeda, Y., Wang, W., Hashiguchi, B. G., Periana, R. A., Szalda, D. J., Muckerman, J. T., & Fujita, E. (2012) · Nature Chemistry · doi:10.1038/nchem.1295 · Cited by 936 · see citing works
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Tanaka, R., Yamashita, M., & Nozaki, K. (2009) · Journal of the American Chemical Society · doi:10.1021/ja903574e · Cited by 904 · see citing works
Alternative Pathways of Carbon Dioxide Fixation: Insights into the Early Evolution of Life?
Fuchs, G. (2011) · Annual Review of Microbiology · doi:10.1146/annurev-micro-090110-102801 · Cited by 726 · see citing works
Schuchmann, K., & Müller, V. (2013) · Science · doi:10.1126/science.1244758 · Cited by 430 · see citing works
Well-Defined Iron Catalyst for Improved Hydrogenation of Carbon Dioxide and Bicarbonate
Ziebart, C., Federsel, C., Anbarasan, P., Jackstell, R., Baumann, W., Spannenberg, A., & Beller, M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja307924a · Cited by 394 · see citing works
Self-citationA Cobalt-Based Catalyst for the Hydrogenation of CO 2 under Ambient Conditions
Jeletic, M. S., Mock, M. T., Appel, A. M., & Linehan, J. C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja406601v · Cited by 391 · see citing works
SCHÜTTE, H., Floßdorf, J., Sahm, H., & Kula, M. (1976) · European Journal of Biochemistry · doi:10.1111/j.1432-1033.1976.tb10108.x · Cited by 379 · see citing works
Formation and Utilization of Poly-β-Hydroxybutyric Acid by Knallgas Bacteria (Hydrogenomonas)
Schlegel, H. G., Gottschalk, G., & Bartha, R. (1961) · Nature · doi:10.1038/191463a0 · Cited by 350 · see citing works
Federsel, C., Ziebart, C., Jackstell, R., et al. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201101343 · Cited by 277 · see citing works
Poehlein, A., Schmidt, S., Kaster, A.-K., Goenrich, M., Vollmers, J., Thürmer, A., Bertsch, J., Schuchmann, K., Voigt, B., Hecker, M., et al. (2012) · PLoS ONE · doi:10.1371/journal.pone.0033439 · Cited by 274 · see citing works
Wang, S., Huang, H., Kahnt, J., Mueller, A. P., Köpke, M., & Thauer, R. K. (2013) · Journal of Bacteriology · doi:10.1128/jb.00678-13 · Cited by 237 · see citing works
Carboxylases in Natural and Synthetic Microbial Pathways
Erb, T. J. (2011) · Applied and Environmental Microbiology · doi:10.1128/aem.05702-11 · Cited by 229 · see citing works
Glueck, S. M., Guemues, S., Fabian, W. M. F., & Faber, K. (2009) · Chemical Society Reviews · doi:10.1039/b807875k · Cited by 153 · see citing works
Kula, M., & Wandrey, C. (1987) · Methods in enzymology on CD-ROM/Methods in enzymology · doi:10.1016/s0076-6879(87)36004-5 · Cited by 130 · see citing works
Clostridium acidurici Electron-Bifurcating Formate Dehydrogenase
Wang, S., Huang, H., Kahnt, J., & Thauer, R. K. (2013) · Applied and Environmental Microbiology · doi:10.1128/aem.02015-13 · Cited by 83 · see citing works
Alissandratos, A., Kim, H. K., Matthews, H., et al. (2012) · Applied and Environmental Microbiology · doi:10.1128/aem.02886-12 · Cited by 80 · see citing works
Improvement for L ‐leucine production in a continuously operated enzyme membrane reactor
Ohshima, T., Wandrey, C., Kula, M., et al. (1985) · Biotechnology and Bioengineering · doi:10.1002/bit.260271118 · Cited by 67 · see citing works
Evolutionary history and biotechnological future of carboxylases
von Borzyskowski, L. S., Rosenthal, R. G., & Erb, T. J. (2013) · Journal of Biotechnology · doi:10.1016/j.jbiotec.2013.05.007 · Cited by 35 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Technologies and perspectives for achieving carbon neutrality
Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330 · see citing works
Enzymatic conversion of carbon dioxide
Shi, J., Jiang, Y., Jiang, Z., Wang, X., Wang, X., Zhang, S., Han, P., & Yang, C. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00182j · Cited by 422 · see citing works
- Authors
- Beller, M., & Bornscheuer, U. T.
- Affiliations
- Universität Greifswald (DE)
- Corresponding author
- Beller, Matthias
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2014-04-06
- Volume
- 53
- Issue
- 18
- Pages
- 4527-4528
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2112866840
- Cited by
- 84
- References
- 19
- Citations by year
- 2026: 2 · 2025: 3 · 2024: 6 · 2023: 5 · 2022: 7 · 2021: 11 · 2020: 4 · 2019: 9 · 2018: 8 · 2017: 11 · 2016: 8 · 2015: 6 · 2014: 4
- FWCI
- 3.97
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- CO2 fixation, hydrogenation, formic acid, hydrogen storage, hydrogen production, organometallic catalysts, room-temperature catalysis, greenhouse gas utilization
- MeSH terms
- Carbon Dioxide, Catalysis, Formates, Hydrogen, Hydrogenation, Organometallic Compounds, Oxidoreductases, Pressure, Temperature
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
