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Aerogels with 3D Ordered Nanofiber Skeletons of Liquid‐Crystalline Nanocellulose Derivatives as Tough and Transparent Insulators

Kobayashi, Yuri, Saito, Tsuguyuki, Isogai, Akira·2014·Angewandte Chemie International Edition

Abstract

Aerogels of high porosity and with a large internal surface area exhibit outstanding performances as thermal, acoustic, or electrical insulators. However, most aerogels are mechanically brittle and optically opaque, and the structural and physical properties of aerogels strongly depend on their densities. The unfavorable characteristics of aerogels are intrinsic to their skeletal structures consisting of randomly interconnected spherical nanoparticles. A structurally new type of aerogel with a three‐dimensionally ordered nanofiber skeleton of liquid‐crystalline nanocellulose (LC‐NCell) is now reported. This LC‐NCell material is composed of mechanically strong, surface‐carboxylated cellulose nanofibers dispersed in a nematic LC order. The LC‐NCell aerogels are transparent and combine mechanical toughness and good insulation properties. These properties of the LC‐NCell aerogels could also be readily controlled.

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Metadata

Authors
Kobayashi, Y., Saito, T., & Isogai, A.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2014-07
Volume
53
Issue
39
Pages
10394-10397
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2144333895
Cited by
566
References
4
FWCI
11.54
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Aerogels with 3D Ordered Nanofiber Skeletons of Liquid‐Crystalline Nanocellulose Derivatives as Tough and Transparent Insulators. https://app.cochat.ai/papers/10.1002/anie.201405123
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Kobayashi, Y., Saito, T., & Isogai, A. (2014). Aerogels with 3D Ordered Nanofiber Skeletons of Liquid‐Crystalline Nanocellulose Derivatives as Tough and Transparent Insulators. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201405123

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