The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al2O3 Catalysts Induced by Strong Metal–Support Interactions
Abstract
In industrially relevant Cu/ZnO/Al 2 O 3 catalysts for methanol synthesis, the strong metal support interaction between Cu and ZnO is known to play a key role. Here we report a detailed chemical transmission electron microscopy study on the nanostructural consequences of the strong metal support interaction in an activated high‐performance catalyst. For the first time, clear evidence for the formation of metastable “graphite‐like” ZnO layers during reductive activation is provided. The description of this metastable layer might contribute to the understanding of synergistic effects between the components of the Cu/ZnO/Al 2 O 3 catalysts.
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Cites
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide
Tauster, S. J., Fung, S. C., & Garten, R. L. (1978) · Journal of the American Chemical Society · doi:10.1021/ja00469a029 · Cited by 3,188
The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts
Behrens, M., Studt, F., Kasatkin, I., Kühl, S., Hävecker, M., Abild-Pedersen, F., Zander, S., Girgsdies, F., Kurr, P., Kniep, B.-L., et al. (2012) · Science · doi:10.1126/science.1219831 · Cited by 2,670
Self-citationStrong Interactions in Supported-Metal Catalysts
Tauster, S. J., Fung, S. C., Baker, R. T. K., & Horsley, J. A. (1981) · Science · doi:10.1126/science.211.4487.1121 · Cited by 1,343
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals
Hansen, P. L., Wagner, J. B., Helveg, S., Rostrup-Nielsen, J. R., Clausen, B. S., & Topsøe, H. (2002) · Science · doi:10.1126/science.1069325 · Cited by 1,261
Bruix, A., Rodriguez, J. A., Ramírez, P. J., Senanayake, S. D., Evans, J., Park, J. B., Stacchiola, D., Liu, P., Hrbek, J., & Illas, F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302070k · Cited by 839
Graphitic Nanofilms as Precursors to Wurtzite Films: Theory
Freeman, C. L., Claeyssens, F., Allan, N. L., & Harding, J. H. (2006) · Physical Review Letters · doi:10.1103/physrevlett.96.066102 · Cited by 581
Junction effect interactions in methanol synthesis catalysts
Frost, J. C. (1988) · Nature · doi:10.1038/334577a0 · Cited by 427
Growth of ZnO thin films—experiment and theory
Claeyssens, F., Freeman, C. L., Allan, N. L., Sun, Y., Ashfold, M. N. R., & Harding, J. H. (2005) · J. Mater. Chem. · doi:10.1039/b414111c · Cited by 417
Atomic-Resolution in Situ Transmission Electron Microscopy of a Promoter of a Heterogeneous Catalyst
Hansen, T. W., Wagner, J. B., Hansen, P. L., Dahl, S., Topsøe, H., & Jacobsen, C. J. H. (2001) · Science · doi:10.1126/science.1064399 · Cited by 405
A model of metal-oxide support interaction for Rh on TiO2
RESASCO, D. (1983) · Journal of Catalysis · doi:10.1016/0021-9517(83)90194-x · Cited by 311
Cited by
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Tuning Selectivity of CO2 Hydrogenation Reactions at the Metal/Oxide Interface
Kattel, S., Liu, P., & Chen, J. G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05362 · Cited by 1,259
Strong Metal–Support Interactions between Pt Single Atoms and TiO2
Han, B., Guo, Y., Huang, Y., Xi, W., Xu, J., Luo, J., Qi, H., Ren, Y., Liu, X., Qiao, B., et al. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202003208 · Cited by 586
Li, Y., Zhang, Y., Qian, K., & Huang, W. (2022) · ACS Catalysis · doi:10.1021/acscatal.1c04854 · Cited by 538
Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol
Li, D., Xu, F., Tang, X., Dai, S., Pu, T., Liu, X., Tian, P., Xuan, F., Xu, Z., Wachs, I. E., et al. (2022) · Nature Catalysis · doi:10.1038/s41929-021-00729-4 · Cited by 519
Metadata
- Authors
- Lunkenbein, T., Schumann, J., Behrens, M., Schlögl, R., & Willinger, M. G.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-02-13
- Volume
- 54
- Issue
- 15
- Pages
- 4544-4548
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2152193384
- Cited by
- 608
- References
- 32
- FWCI
- 12.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lunkenbein, T., Schumann, J., Behrens, M., Schlögl, R., & Willinger, M. G. (2015). Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al2O3 Catalysts Induced by Strong Metal–Support Interactions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201411581
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