The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Surface‐Specific Functionalization of Nanoscale Metal–Organic Frameworks
Abstract
A method for modifying the external surfaces of a series of nanoscale metal–organic frameworks (MOFs) with 1,2‐dioleoyl‐sn‐glycero‐3‐phosphate (DOPA) is presented. A series of zirconium‐based nanoMOFs of the same topology (UiO‐66, UiO‐67, and BUT‐30) were synthesized, isolated as aggregates, and then conjugated with DOPA to create stably dispersed colloids. BET surface area analysis revealed that these structures maintain their porosity after surface functionalization, providing evidence that DOPA functionalization only occurs on the external surface. Additionally, dye‐labeled ligand loading studies revealed that the density of DOPA on the surface of the nanoscale MOF correlates to the density of metal nodes on the surface of each MOF. Importantly, the surface modification strategy described will allow for the general and divergent synthesis and study of a wide variety of nanoscale MOFs as stable colloidal materials.
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Cites
Metal-organic framework materials as catalysts
Lee, J., Farha, O. K., Roberts, J., Scheidt, K. A., Nguyen, S. T., & Hupp, J. T. (2009) · Chemical Society Reviews · doi:10.1039/b807080f · Cited by 7,969
Self-citationHorike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
Cited by
Metal–Organic Framework Nanoparticles
Wang, S., McGuirk, C. M., d'Aquino, A., Mason, J. A., & Mirkin, C. A. (2018) · Advanced Materials · doi:10.1002/adma.201800202 · Cited by 833
Self-citationApplication of zirconium MOFs in drug delivery and biomedicine
Abánades Lázaro, I., & Forgan, R. S. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2018.09.009 · Cited by 678
Metal‐Organic Framework Nanoparticles in Photodynamic Therapy: Current Status and Perspectives
Lismont, M., Dreesen, L., & Wuttke, S. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201606314 · Cited by 622
Ma, D., Peh, S. B., Han, G., & Chen, S. B. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b14223 · Cited by 377
Wuttke, S., Lismont, M., Escudero, A., Rungtaweevoranit, B., & Parak, W. J. (2017) · Biomaterials · doi:10.1016/j.biomaterials.2017.01.025 · Cited by 286
Metadata
- Authors
- Wang, S., Morris, W., Liu, Y., McGuirk, C. M., Zhou, Y., Hupp, J. T., Farha, O. K., & Mirkin, C. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-10-23
- Volume
- 54
- Issue
- 49
- Pages
- 14738-14742
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2103204348
- Cited by
- 182
- References
- 2
- FWCI
- 6.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, S., Morris, W., Liu, Y., McGuirk, C. M., Zhou, Y., Hupp, J. T., Farha, O. K., & Mirkin, C. A. (2015). Surface‐Specific Functionalization of Nanoscale Metal–Organic Frameworks. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201506888
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