The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide‐Derived Copper
Open accessAbstract
Oxide‐derived copper (OD‐Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at −0.3 V (vs. RHE). By using static headspace‐gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD‐Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at −0.33 V (vs. RHE). We show that acetaldehyde forms at low steady‐state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification. Our results represent an important step towards understanding the CO reduction mechanism on OD‐Cu electrodes.
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How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
Peterson, A. A., Abild-Pedersen, F., Studt, F., Rossmeisl, J., & Nørskov, J. K. (2010) · Energy & Environmental Science · doi:10.1039/c0ee00071j · Cited by 3,784
Self-citationNew insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
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Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
Li, C. W., Ciston, J., & Kanan, M. W. (2014) · Nature · doi:10.1038/nature13249 · Cited by 1,728
Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
Peterson, A. A., & Nørskov, J. K. (2012) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201461p · Cited by 1,667
Self-citationTheoretical Considerations on the Electroreduction of CO to C 2 Species on Cu(100) Electrodes
Calle‐Vallejo, F., & Koper, M. T. M. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201301470 · Cited by 941
Active and Selective Conversion of CO 2 to CO on Ultrathin Au Nanowires
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Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts
Verdaguer-Casadevall, A., Li, C. W., Johansson, T. P., Scott, S. B., McKeown, J. T., Kumar, M., Stephens, I. E. L., Kanan, M. W., & Chorkendorff, I. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06227 · Cited by 645
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Cited by
Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Self-citationProgress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Self-citationDesigning materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
Sun, Z., Ma, T., Tao, H., Fan, Q., & Han, B. (2017) · Chem · doi:10.1016/j.chempr.2017.09.009 · Cited by 1,224
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles
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Metadata
- Authors
- Bertheussen, E., Verdaguer‐Casadevall, A., Ravasio, D., Montoya, J. H., Trimarco, D. B., Roy, C., Meier, S., Wendland, J., Nørskov, J. K., Stephens, I. E. L., & Chorkendorff, I.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2015-12-21
- Volume
- 55
- Issue
- 4
- Pages
- 1450-1454
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2257637705
- Cited by
- 224
- References
- 8
- FWCI
- 3.62
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Bertheussen, E., Verdaguer‐Casadevall, A., Ravasio, D., Montoya, J. H., Trimarco, D. B., Roy, C., Meier, S., Wendland, J., Nørskov, J. K., Stephens, I. E. L., & Chorkendorff, I. (2016). Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide‐Derived Copper. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201508851
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