The DOI matches its Crossref record; 30 of the 30 references it cites were found in a registry or an index.
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO2 over Cu Nanowire Arrays
Abstract
In this work, the effect of Cu nanowire morphology on the selective electrocatalytic reduction of CO 2 is presented. Cu nanowire arrays were prepared through a two‐step synthesis of Cu(OH)2 and CuO nanowire arrays on Cu foil substrates and a subsequent electrochemical reduction of the CuO nanowire arrays to Cu nanowire arrays. By this simple synthesis method, Cu nanowire array electrodes with different length and density were able to be controllably synthesized. We show that the selectivity for hydrocarbons (ethylene, n‐propanol, ethane, and ethanol) on Cu nanowire array electrodes at a fixed potential can be tuned by systematically altering the Cu nanowire length and density. The nanowire morphology effect is linked to the increased local pH in the Cu nanowire arrays and a reaction scheme detailing the local pH‐induced formation of C 2 products is also presented by a preferred CO dimerization pathway.
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Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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Aqueous CO2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Large-Scale and Highly Selective CO2 Electrocatalytic Reduction on Nickel Single-Atom Catalyst
Zheng, T., Jiang, K., Ta, N., Hu, Y., Zeng, J., Liu, J., & Wang, H. (2019) · Joule · doi:10.1016/j.joule.2018.10.015 · Cited by 887
Hoang, T. T. H., Verma, S., Ma, S., Fister, T. T., Timoshenko, J., Frenkel, A. I., Kenis, P. J. A., & Gewirth, A. A. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b01868 · Cited by 852
Li, F., Chen, L., Knowles, G. P., MacFarlane, D. R., & Zhang, J. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201608279 · Cited by 631
Huang, J., Mensi, M., Oveisi, E., Mantella, V., & Buonsanti, R. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b12381 · Cited by 594
Metadata
- Authors
- Ma, M., Djanashvili, K., & Smith, W. A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-04-21
- Volume
- 55
- Issue
- 23
- Pages
- 6680-6684
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2340533519
- Cited by
- 640
- References
- 30
- FWCI
- 16.36
- Type
- journal article
- Language
- en
- Open access
- closed
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