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Selective and Efficient Reduction of Carbon Dioxide to Carbon Monoxide on Oxide‐Derived Nanostructured Silver Electrocatalysts
Open accessAbstract
In this work, the selective electrocatalytic reduction of carbon dioxide to carbon monoxide on oxide‐derived silver electrocatalysts is presented. By a simple synthesis technique, the overall high faradaic efficiency for CO production on the oxide‐derived Ag was shifted by more than 400 mV towards a lower overpotential compared to that of untreated Ag. Notably, the Ag resulting from Ag oxide is capable of electrochemically reducing CO 2 to CO with approximately 80 % catalytic selectivity at a moderate overpotential of 0.49 V, which is much higher than that (ca. 4 %) of untreated Ag under identical conditions. Electrokinetic studies show that the improved catalytic activity is ascribed to the enhanced stabilization of COOH . intermediate. Furthermore, highly nanostructured Ag is likely able to create a high local pH near the catalyst surface, which may also facilitate the catalytic activity for the reduction of CO 2 with suppressed H 2 evolution.
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Metadata
- Authors
- Ma, M., Trześniewski, B. J., Xie, J., & Smith, W. A.
- Affiliations
- China University of Petroleum, East China (CN)
- Delft University of Technology (NL)
- Eindhoven University of Technology (NL)
- Corresponding author
- Smith, Wilson A.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2016-07-05
- Volume
- 55
- Issue
- 33
- Pages
- 9748-9752
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2470317005
- Cited by
- 530
- References
- 43
- Citations by year
- 2026: 17 · 2025: 34 · 2024: 49 · 2023: 50 · 2022: 43 · 2021: 72 · 2020: 81 · 2019: 78 · 2018: 62 · 2017: 38 · 2016: 6
- FWCI
- 16.65
- Type
- journal article
- Language
- en
- Open access
- green
- research.tue.nl
- Licence
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- TU/e Research Portal (publishedVersion, other-oa)
- TU/e Research Portal (submittedVersion)
- TU/e Research Portal (submittedVersion, other-oa)
- Funders
- CSC
- NWO VENI
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- electrochemical CO2 reduction, carbon monoxide production, silver electrocatalyst, silver nanostructures, COOH intermediate, Faradaic efficiency, overpotential, local pH, hydrogen evolution suppression, CO selectivity
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