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Hollow Chevrel‐Phase NiMo3S4 for Hydrogen Evolution in Alkaline Electrolytes

Jiang, Jun, Gao, Minrui, Sheng, Wenchao, Yan, Yushan·2016·Angewandte Chemie International Edition

Abstract

Electrochemical water splitting to generate molecular hydrogen requires catalysts that are cheap, active, and stable, particularly for alkaline electrolyzers, where the cathodic hydrogen evolution reaction is slower in base than in acid even on platinum. Herein, we describe the synthesis of new hollow Chevrel‐phase NiMo 3 S 4 and its alkaline hydrogen evolution reaction (HER) performance: onset potential of −59 mV, Tafel slope of 98 mV per decade, and exchange current density of 3.9×10−2 mA cm−2. This Chevrel‐phase chalcogenide also demonstrates outstanding long‐term stability under harsh HER cycling conditions. Chevrel‐phase nanomaterials show promise as efficient, low‐cost catalysts for alkaline electrolyzers.

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Metadata

Authors
Jiang, J., Gao, M., Sheng, W., & Yan, Y.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2016-11-02
Volume
55
Issue
49
Pages
15240-15245
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2547650778
Cited by
163
References
10
FWCI
7.51
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Hollow Chevrel‐Phase NiMo3S4 for Hydrogen Evolution in Alkaline Electrolytes. https://app.cochat.ai/papers/10.1002/anie.201607651
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Jiang, J., Gao, M., Sheng, W., & Yan, Y. (2016). Hollow Chevrel‐Phase NiMo3S4 for Hydrogen Evolution in Alkaline Electrolytes. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201607651

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