The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Low‐Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst
Abstract
Herein we describe the first homogeneous non‐noble metal catalyst for the hydrogenation of CO 2 to methanol. The catalyst is formed in situ from [Co(acac)3], Triphos, and HNTf 2 and enables the reaction to be performed at 100 °C without a decrease in activity. Kinetic studies suggest an inner‐sphere mechanism, and in situ NMR and MS experiments reveal the formation of the active catalyst through slow removal of the acetylacetonate ligands.
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Citations
Cites
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Negative emissions physically needed to keep global warming below 2 °C
Gasser, T., Guivarch, C., Tachiiri, K., Jones, C. D., & Ciais, P. (2015) · Nature Communications · doi:10.1038/ncomms8958 · Cited by 374
Cited by
Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
Kar, S., Goeppert, A., Kothandaraman, J., & Prakash, G. K. S. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02066 · Cited by 258
Wu, Y., Zhao, Y., Li, R., Yu, B., Chen, Y., Liu, X., Wu, C., Luo, X., & Liu, Z. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01422 · Cited by 126
Metadata
- Authors
- Schneidewind, J., Adam, R., Baumann, W., Jackstell, R., & Beller, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2017-01-12
- Volume
- 56
- Issue
- 7
- Pages
- 1890-1893
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2575533503
- Cited by
- 280
- References
- 2
- FWCI
- 12.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Schneidewind, J., Adam, R., Baumann, W., Jackstell, R., & Beller, M. (2017). Low‐Temperature Hydrogenation of Carbon Dioxide to Methanol with a Homogeneous Cobalt Catalyst. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201609077
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