The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide
Abstract
Mn(I)-PNP pincer catalyzed sequential one-pot homogeneous CO 2 hydrogenation to CH 3 OH by molecular H 2 is demonstrated. The hydrogenation consists of two parts—N-formylation of an amine utilizing CO 2 and H 2, and subsequent formamide reduction to CH 3 OH, regenerating the amine in the process. A reported air-stable and well-defined Mn-PNP pincer complex was found active for the catalysis of both steps. CH 3 OH yields up to 84% and 71% (w.r.t amine) were obtained, when benzylamine and morpholine were used as amines, respectively; and a TON of up to 36 was observed. In our opinion, this study represents an important development in the nascent field of base-metal-catalyzed homogeneous CO 2 hydrogenation to CH 3 OH.
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An overview of current status of carbon dioxide capture and storage technologies
Leung, D. Y. C., Caramanna, G., & Maroto-Valer, M. M. (2014) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2014.07.093 · Cited by 3,198
The Active Site of Methanol Synthesis over Cu/ZnO/Al 2 O 3 Industrial Catalysts
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Direct Capture of CO2 from Ambient Air
Sanz-Pérez, E. S., Murdock, C. R., Didas, S. A., & Jones, C. W. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00173 · Cited by 2,406
A Review of CO2 Capture by Absorption and Adsorption
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Self-citationRecycling of carbon dioxide to methanol and derived products – closing the loop
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Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO 2
Graciani, J., Mudiyanselage, K., Xu, F., Baber, A. E., Evans, J., Senanayake, S. D., Stacchiola, D. J., Liu, P., Hrbek, J., Sanz, J. F., et al. (2014) · Science · doi:10.1126/science.1253057 · Cited by 1,452
Utilisation of CO2 as a chemical feedstock: opportunities and challenges
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Cited by
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Kar, S., Goeppert, A., Kothandaraman, J., & Prakash, G. K. S.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-23
- Volume
- 7
- Issue
- 9
- Pages
- 6347-6351
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2745408185
- Cited by
- 258
- References
- 41
- FWCI
- 9.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kar, S., Goeppert, A., Kothandaraman, J., & Prakash, G. K. S. (2017). Manganese-Catalyzed Sequential Hydrogenation of CO2 to Methanol via Formamide. ACS Catalysis. https://doi.org/10.1021/acscatal.7b02066
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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