The DOI matches its Crossref record.
C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation
Abstract
Rhodium(III)-catalyzed direct functionalization of C-H bonds under oxidative conditions leading to C-C, C-N, and C-O bond formation is reviewed. Various arene substrates bearing nitrogen and oxygen directing groups are covered in their coupling with unsaturated partners such as alkenes and alkynes. The facile construction of C-E (E = C, N, S, or O) bonds makes Rh(III) catalysis an attractive step-economic approach to value-added molecules from readily available starting materials. Comparisons and contrasts between rhodium(III) and palladium(II)-catalyzed oxidative coupling are made. The remarkable diversity of structures accessible is demonstrated with various recent examples, with a proposed mechanism for each transformation being briefly summarized (critical review, 138 references).
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Carboxylate-Assisted Ruthenium-Catalyzed Alkyne Annulations by C–H/Het–H Bond Functionalizations
Ackermann, L. (2014) · Accounts of Chemical Research · doi:10.1021/ar3002798 · Cited by 1,640
General Enantioselective C−H Activation with Efficiently Tunable Cyclopentadienyl Ligands
Jia, Z., Merten, C., Gontla, R., Daniliuc, C. G., Antonchick, A. P., & Waldmann, H. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201611981 · Cited by 336
Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Hou, S., Dong, J., & Zhao, B. (2020) · Advanced Materials · doi:10.1002/adma.201806163 · Cited by 142
Metadata
- Authors
- Song, G., Wang, F., & Li, X.
- Venue
- Chemical Society Reviews
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2012
- Volume
- 41
- Issue
- 9
- Pages
- 3651
- ISSN
- 0306-0012 (ISSN-L)
- 1460-4744
- OpenAlex
- W2104742517
- Cited by
- 2,302
- References
- 0
- FWCI
- 9.24
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation. https://app.cochat.ai/papers/10.1039/c2cs15281a
- The paper
- Song, G., Wang, F., & Li, X. (2012). C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation. Chemical Society Reviews. https://doi.org/10.1039/c2cs15281a
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
