The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Nanosized Metal Phosphides Embedded in Nitrogen‐Doped Porous Carbon Nanofibers for Enhanced Hydrogen Evolution at All pH Values
Abstract
Transition‐metal phosphides (TMPs) have emerged as promising catalyst candidates for the hydrogen evolution reaction (HER). Although numerous methods have been investigated to obtain TMPs, most rely on traditional synthetic methods that produce materials that are inherently deficient with respect to electrical conductivity. An electrospinning‐based reduction approach is presented, which generates nickel phosphide nanoparticles in N‐doped porous carbon nanofibers (Ni 2 P@NPCNFs) in situ. Ni 2 P nanoparticles are protected from irreversible fusion and aggregation in subsequent high‐temperature pyrolysis. The resistivity of Ni 2 P@NPCNFs (5.34 Ω cm) is greatly decreased by 10 4 times compared to Ni 2 P (>10 4 Ω cm) because N‐doped carbon NFs are incorporated. As an electrocatalyst for HER, Ni 2 P@NPCNFs reveal remarkable performance compared to other previously reported catalysts in acidic media. Additionally, it offers excellent catalytic ability and durability in both neutral and basic media. Encouraged by the excellent electrocatalytic performance of Ni 2 P@NPCNFs, a series of pea‐like M x P@NPCNFs, including Fe 2 P@NPCNFs, Co 2 P@NPCNFs, and Cu 3 P@NPCNFs, were synthesized by the same method. Detailed characterization suggests that the newly developed method could render combinations of ultrafine metal phosphides with porous carbon accessible; thereby, extending opportunities in electrocatalytic applications.
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Cites
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
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Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
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Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
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Cited by
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Support and Interface Effects in Water‐Splitting Electrocatalysts
Zhang, J., Zhang, Q., & Feng, X. (2019) · Advanced Materials · doi:10.1002/adma.201808167 · Cited by 916
Ouyang, T., Ye, Y., Wu, C., Xiao, K., & Liu, Z. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201814262 · Cited by 804
Recent advances in transition metal-based electrocatalysts for alkaline hydrogen evolution
Chen, Z., Duan, X., Wei, W., Wang, S., & Ni, B.-J. (2019) · Journal of Materials Chemistry A · doi:10.1039/c9ta03220g · Cited by 753
CoP‐Doped MOF‐Based Electrocatalyst for pH‐Universal Hydrogen Evolution Reaction
Liu, T., Li, P., Yao, N., Cheng, G., Chen, S., Luo, W., & Yin, Y. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201901409 · Cited by 606
Metadata
- Authors
- Wang, M., Ye, C., Liu, H., Xu, M., & Bao, S.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2018-01-12
- Volume
- 57
- Issue
- 7
- Pages
- 1963-1967
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2772251759
- Cited by
- 320
- References
- 12
- FWCI
- 11.46
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, M., Ye, C., Liu, H., Xu, M., & Bao, S. (2018). Nanosized Metal Phosphides Embedded in Nitrogen‐Doped Porous Carbon Nanofibers for Enhanced Hydrogen Evolution at All pH Values. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201710150
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