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Nickel Doping in Atomically Thin Tin Disulfide Nanosheets Enables Highly Efficient CO2 Reduction

Zhang, An, He, Rong, Li, Huiping, Chen, Yijun, Kong, Taoyi, Li, Kan, Ju, Huanxin, Zhu, Junfa, Zhu, Wenguang, Zeng, Jie·2018·Angewandte Chemie International Edition

Abstract

Engineering electronic properties by elemental doping is a direct strategy to design efficient catalysts towards CO 2 electroreduction. Atomically thin SnS 2 nanosheets were modified by Ni doping for efficient electroreduction of CO 2. The introduction of Ni into SnS 2 nanosheets significantly enhanced the current density and Faradaic efficiency for carbonaceous product relative to pristine SnS 2 nanosheets. When the Ni content was 5 atm %, the Ni‐doped SnS 2 nanosheets achieved a remarkable Faradaic efficiency of 93 % for carbonaceous product with a current density of 19.6 mA cm−2 at −0.9 V vs. RHE. A mechanistic study revealed that the Ni doping gave rise to a defect level and lowered the work function of SnS 2 nanosheets, resulting in the promoted CO 2 activation and thus improved performance in CO 2 electroreduction.

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Metadata

Authors
Zhang, A., He, R., Li, H., Chen, Y., Kong, T., Li, K., Ju, H., Zhu, J., Zhu, W., & Zeng, J.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2018-08-07
Volume
57
Issue
34
Pages
10954-10958
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2810830133
Cited by
241
References
4
FWCI
7.01
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Nickel Doping in Atomically Thin Tin Disulfide Nanosheets Enables Highly Efficient CO2 Reduction. https://app.cochat.ai/papers/10.1002/anie.201806043
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Zhang, A., He, R., Li, H., Chen, Y., Kong, T., Li, K., Ju, H., Zhu, J., Zhu, W., & Zeng, J. (2018). Nickel Doping in Atomically Thin Tin Disulfide Nanosheets Enables Highly Efficient CO2 Reduction. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201806043

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