Polymerization of rac‐Lactide Using Achiral Iron Complexes: Access to Thermally Stable Stereocomplexes
Abstract
Enantiopure poly(lactic acid) (PLA) can form stereocomplexes when enantiomeric PLA chains are mixed in equivalent amounts. Such materials provide interesting features that might be suitable for numerous applications. Despite several advantages, the main drawback of PLA is its narrow window of processing, thus limiting its use for industrial applications. Reported herein are achiral iron complexes, that are highly active, productive, and stereoselective under mild reaction conditions for the ring‐opening polymerization of lactide. The corresponding catalytic systems enable the production of stereoblock polymers with high molecular weights, allowing the formation of thermally stable and industrially relevant stereocomplexes.
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Only a few iron catalysts were demonstrated to give reasonably good activity and control over the molar mass of the obtained polymer.
“Only a few catalysts were demonstrated to give reasonably good activity and control over the molar mass of the obtained polymer.”
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- Authors
- Marin, P., Tschan, M. J. ‐., Isnard, F., Robert, C., Haquette, P., Trivelli, X., Chamoreau, L., Guérineau, V., del Rosal, I., Maron, L., Venditto, V., & Thomas, C. M.
- Affiliations
- Centre National de la Recherche Scientifique (FR)
- Université Paris-Sud (FR)
- Université de Toulouse INSA, UPS; LPCNO (IRSAMC) 135 avenue de Rangueil 31077 Toulouse France
- University of Salerno (IT)
- Corresponding author
- Venditto, Vincenzo
- Thomas, Christophe M.
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-04-12
- Volume
- 58
- Issue
- 36
- Pages
- 12585-12589
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2940262419
- Cited by
- 74
- References
- 68
- Citations by year
- 2026: 4 · 2025: 13 · 2024: 9 · 2023: 10 · 2022: 12 · 2021: 11 · 2020: 7 · 2019: 8
- FWCI
- 2.69
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- HAL (submittedVersion)
- Funders
- Agence Nationale de la Recherche (ANR-10-PDOC-010-01)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
- Keywords
- rac-lactide, ring-opening polymerization, stereocomplex, polylactic acid, stereoblock polymers, stereoselective polymerization, thermal stability
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