Cited by 337Electrocatalysts for Energy ConversionHydrogen Storage and MaterialsCO2 Reduction Techniques and Catalysts

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Boron‐Induced Electronic‐Structure Reformation of CoP Nanoparticles Drives Enhanced pH‐Universal Hydrogen Evolution

Cao, Erping, Chen, Zhimin, Wu, Hao, Yu, Peng, Wang, Ying, Xiao, Fei, Chen, Shuo, Du, Shichao, Xie, Ying, Wu, Yiqun, Ren, Zhiyu·2020·Angewandte Chemie International Edition

DOI 10.1002/anie.201915254

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Abstract

Even though transition‐metal phosphides (TMPs) have been developed as promising alternatives to Pt catalyst for the hydrogen evolution reaction (HER), further improvement of their performance requires fine regulation of the TMP sites related to their specific electronic structure. Herein, for the first time, boron (B)‐modulated electrocatalytic characteristics in CoP anchored on the carbon nanotubes (B‐CoP/CNT) with impressive HER activities over a wide pH range are reported. The HER performance surpasses commercial Pt/C in both neutral and alkaline media at large current density (>100 mA cm−2). A combined experimental and theoretical study identified that the B dopant could reform the local electronic configuration and atomic arrangement of bonded Co and adjacent P atoms, enhance the electrons’ delocalization capacity of Co atoms for high electrical conductivity, and optimize the free energy of H adsorption and H 2 desorption on the active sites for better HER kinetics.

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Authors: Cao, E., Chen, Z., Wu, H., Yu, P., Wang, Y., Xiao, F., Chen, S., Du, S., Xie, Y., Wu, Y., & Ren, Z.
Affiliations: Heilongjiang University (CN)
Harbin Normal University (CN)
Corresponding author: Chen, Zhimin
Ren, Zhiyu
ORCID: Chen, Zhimin
Yu, Peng
Wang, Ying
Xiao, Fei
Xie, Ying
Wu, Yiqun
Ren, Zhiyu
Venue: Angewandte Chemie International Edition
Publisher: Wiley
Published: 2020-01-24
Volume: 59
Issue: 10
Pages: 4154-4160
ISSN: 1433-7851 (ISSN-L)
1521-3773
DOI: 10.1002/anie.201915254
OpenAlex: W2996695560
Cited by: 337
References: 68
Citations by year: 2026: 20 · 2025: 45 · 2024: 61 · 2023: 47 · 2022: 78 · 2021: 69 · 2020: 17
FWCI: 8.72
Type: journal article
Language: en
Open access: closed
Licence: onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations: Angewandte Chemie International Edition (publishedVersion)
PubMed (publishedVersion)
Funders: National Natural Science Foundation of China (21573062, 51002046, 21901065)
Natural Science Foundation of Heilongjiang Province (B2018008)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Keywords: hydrogen evolution reaction, cobalt phosphide nanoparticles, boron doping, transition metal phosphides, carbon nanotubes, electrocatalysis, pH universality, electronic structure modulation, H* adsorption free energy, hydrogen desorption, platinum-free catalysts, alkaline water electrolysis

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Boron‐Induced Electronic‐Structure Reformation of CoP Nanoparticles Drives Enhanced pH‐Universal Hydrogen Evolution

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