The DOI matches its Crossref record; 45 of the 45 references it cites were found in a registry or an index.
Regulating Interfacial Chemistry in Lithium‐Ion Batteries by a Weakly Solvating Electrolyte**
Abstract
The performance of Li‐ion batteries (LIBs) is highly dependent on their interfacial chemistry, which is regulated by electrolytes. Conventional electrolyte typically contains polar solvents to dissociate Li salts. Herein we report a weakly solvating electrolyte (WSE) that consists of a pure non‐polar solvent, which leads to a peculiar solvation structure where ion pairs and aggregates prevail under a low salt concentration of 1.0 M. Importantly, WSE forms unique anion‐derived interphases on graphite electrodes that exhibit fast‐charging and long‐term cycling characteristics. First‐principles calculations unravel a general principle that the competitive coordination between anions and solvents to Li ions is the origin of different interfacial chemistries. By bridging the gap between solution thermodynamics and interfacial chemistry in batteries, this work opens a brand‐new way towards precise electrolyte engineering for energy storage devices with desired properties.
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Cites
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
Cheng, X.-B., Zhang, R., Zhao, C.-Z., & Zhang, Q. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00115 · Cited by 6,197
Self-citation30 Years of Lithium‐Ion Batteries
Li, M., Lu, J., Chen, Z., & Amine, K. (2018) · Advanced Materials · doi:10.1002/adma.201800561 · Cited by 6,039
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821
Pathways for practical high-energy long-cycling lithium metal batteries
Liu, J., Bao, Z., Cui, Y., Dufek, E. J., Goodenough, J. B., Khalifah, P., Li, Q., Liaw, B. Y., Liu, P., Manthiram, A., et al. (2019) · Nature Energy · doi:10.1038/s41560-019-0338-x · Cited by 3,412
Performance and cost of materials for lithium-based rechargeable automotive batteries
Schmuch, R., Wagner, R., Hörpel, G., Placke, T., & Winter, M. (2018) · Nature Energy · doi:10.1038/s41560-018-0107-2 · Cited by 3,233
High rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Designing solid-state electrolytes for safe, energy-dense batteries
Zhao, Q., Stalin, S., Zhao, C.-Z., & Archer, L. A. (2020) · Nature Reviews Materials · doi:10.1038/s41578-019-0165-5 · Cited by 2,372
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Review—SEI: Past, Present and Future
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Cited by
Challenges and development of lithium-ion batteries for low temperature environments
Piao, N., Gao, X., Yang, H., Guo, Z., Hu, G., Cheng, H.-M., & Li, F. (2022) · eTransportation · doi:10.1016/j.etran.2021.100145 · Cited by 324
Zhao, Y., Zhou, T., Mensi, M., Choi, J. W., & Coskun, A. (2023) · Nature Communications · doi:10.1038/s41467-023-35934-1 · Cited by 279
Wang, S., Wu, F., Takyi-Aninakwa, P., Fernandez, C., Stroe, D.-I., & Huang, Q. (2023) · Energy · doi:10.1016/j.energy.2023.128677 · Cited by 281
Wu, Y., Hu, Q., Liang, H., Wang, A., Xu, H., Wang, L., & He, X. (2023) · Advanced Energy Materials · doi:10.1002/aenm.202300259 · Cited by 270
Nan, B., Chen, L., Rodrigo, N. D., Borodin, O., Piao, N., Xia, J., Pollard, T., Hou, S., Zhang, J., Ji, X., et al. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202205967 · Cited by 222
Self-citation
Metadata
- Authors
- Yao, Y., Chen, X., Yan, C., Zhang, X., Cai, W., Huang, J., & Zhang, Q.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-11-19
- Volume
- 60
- Issue
- 8
- Pages
- 4090-4097
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3089077108
- Cited by
- 855
- References
- 45
- FWCI
- 28.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yao, Y., Chen, X., Yan, C., Zhang, X., Cai, W., Huang, J., & Zhang, Q. (2021). Regulating Interfacial Chemistry in Lithium‐Ion Batteries by a Weakly Solvating Electrolyte**. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202011482
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