The DOI matches its Crossref record; 46 of the 46 references it cites were found in a registry or an index.
Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries
Open accessAbstract
Fluorination of ether solvents is an effective strategy to improve the electrochemical stability of non-aqueous electrolyte solutions in lithium metal batteries. However, excessive fluorination detrimentally impacts the ionic conductivity of the electrolyte, thus limiting the battery performance. Here, to maximize the electrolyte ionic conductivity and electrochemical stability, we introduce the targeted trifluoromethylation of 1,2-dimethoxyethane to produce 1,1,1-trifluoro-2,3-dimethoxypropane (TFDMP). TFDMP is used as a solvent to prepare a 2 M non-aqueous electrolyte solution comprising bis(fluorosulfonyl)imide salt. This electrolyte solution shows an ionic conductivity of 7.4 mS cm–1 at 25 °C, an oxidation stability up to 4.8 V and an efficient suppression of Al corrosion. When tested in a coin cell configuration at 25 °C using a 20 μm Li metal negative electrode, a high mass loading LiNi 0.8 Co 0.1 Mn 0.1 O 2-based positive electrode (20 mg cm–2) with a negative/positive (N/P) capacity ratio of 1, discharge capacity retentions (calculated excluding the initial formation cycles) of 81% after 200 cycles at 0.1 A g–1 and 88% after 142 cycles at 0.2 A g–1 are achieved.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Reviving the lithium metal anode for high-energy batteries
Lin, D., Liu, Y., & Cui, Y. (2017) · Nature Nanotechnology · doi:10.1038/nnano.2017.16 · Cited by 6,763
Promise and reality of post-lithium-ion batteries with high energy densities
Choi, J. W., & Aurbach, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.13 · Cited by 5,110
Self-citationHigh rate and stable cycling of lithium metal anode
Qian, J., Henderson, W. A., Xu, W., Bhattacharya, P., Engelhard, M., Borodin, O., & Zhang, J.-G. (2015) · Nature Communications · doi:10.1038/ncomms7362 · Cited by 2,561
Advances and issues in developing salt-concentrated battery electrolytes
Yamada, Y., Wang, J., Ko, S., Watanabe, E., & Yamada, A. (2019) · Nature Energy · doi:10.1038/s41560-019-0336-z · Cited by 1,788
Yamada, Y., Furukawa, K., Sodeyama, K., Kikuchi, K., Yaegashi, M., Tateyama, Y., & Yamada, A. (2014) · Journal of the American Chemical Society · doi:10.1021/ja412807w · Cited by 1,525
Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries
Adams, B. D., Zheng, J., Ren, X., Xu, W., & Zhang, J. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702097 · Cited by 1,499
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
Zheng, J., Engelhard, M. H., Mei, D., Jiao, S., Polzin, B. J., Zhang, J.-G., & Xu, W. (2017) · Nature Energy · doi:10.1038/nenergy.2017.12 · Cited by 1,343
High‐Voltage Lithium‐Metal Batteries Enabled by Localized High‐Concentration Electrolytes
Chen, S., Zheng, J., Mei, D., Han, K. S., Engelhard, M. H., Zhao, W., Xu, W., Liu, J., & Zhang, J. (2018) · Advanced Materials · doi:10.1002/adma.201706102 · Cited by 1,328
Yu, Z., Wang, H., Kong, X., Huang, W., Tsao, Y., Mackanic, D. G., Wang, K., Wang, X., Huang, W., Choudhury, S., et al. (2020) · Nature Energy · doi:10.1038/s41560-020-0634-5 · Cited by 1,228
Cited by
Fluorination in advanced battery design
Wang, Y., Wu, Z., Azad, F. M., Zhu, Y., Wang, L., Hawker, C. J., Whittaker, A. K., Forsyth, M., & Zhang, C. (2023) · Nature Reviews Materials · doi:10.1038/s41578-023-00623-4 · Cited by 333
Electrolytomics: A Unified Big Data Approach for Electrolyte Design and Discovery
Kumar, R., Vu, M. C., Ma, P., & Amanchukwu, C. V. (2025) · Chemistry of Materials · doi:10.1021/acs.chemmater.4c03196 · Cited by 45
Metadata
- Authors
- Zhao, Y., Zhou, T., Mensi, M., Choi, J. W., & Coskun, A.
- Venue
- Nature Communications
- Published
- 2023-01-18
- Volume
- 14
- Issue
- 1
- Pages
- 299-299
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W4317234390
- Cited by
- 279
- References
- 46
- FWCI
- 20.45
- Type
- journal article
- Language
- en
- Open access
- gold
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries. https://app.cochat.ai/papers/10.1038/s41467-023-35934-1
- The paper
- Zhao, Y., Zhou, T., Mensi, M., Choi, J. W., & Coskun, A. (2023). Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries. Nature Communications. https://doi.org/10.1038/s41467-023-35934-1
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
