Cited by 680Advanced oxidation water treatmentElectrocatalysts for Energy ConversionPolyoxometalates: Synthesis and Applications

Inside Cover: Mn−O Covalency Governs the Intrinsic Activity of Co‐Mn Spinel Oxides for Boosted Peroxymonosulfate Activation (Angew. Chem. Int. Ed. 1/2021)

Guo, Zhi‐Yan, Li, Chen‐Xuan, Gao, Miao, Han, Xiao, Zhang, Ying‐Jie, Zhang, Wen‐Jun, Li, Wen‐Wei·2021·Angewandte Chemie International Edition

Abstract

Bimetallic spinel oxides are efficient catalysts for peroxymonosulfate (PMS) activation but the catalytic mechanism is unclear. The critical role of Mn−O covalency in determining the intrinsic activity of Co3−xMnxO4 and a new mechanism of Co–Mn synergy are revealed by Wen-Wei Li and co-workers in their Research Article on page 274. Co strengthens Mn−O covalency in the octahedral configuration of Co3−xMnxO4, which lowers the charge transfer energy of the MnOh–PMS interaction and drastically accelerates MnVI/MnIII redox cycling.

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Crossref · 10.1002/anie.202014556

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Authors
Guo, Z., Li, C., Gao, M., Han, X., Zhang, Y., Zhang, W., & Li, W.
Affiliations
  • Department of Environmental Science and Engineering University of Science & Technology of China Hefei 230026 China
  • University of Science and Technology of China (CN)
  • Department of Materials Science and Engineering City University of Hong Kong, Hong Kong SAR China
Corresponding author
Li, Wen‐Wei
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-11-12
Volume
60
Issue
1
Pages
2-2
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3118166060
Cited by
680
References
0
Citations by year
2026: 9 · 2025: 25 · 2024: 51 · 2023: 90 · 2022: 177 · 2021: 327 · 2020: 1
FWCI
45.59
Type
journal article
Language
en
Open access
closed
Locations
Angewandte Chemie International Edition (publishedVersion)
Topics
  • Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Materials Science › Materials Chemistry › Polyoxometalates: Synthesis and Applications
Keywords
peroxymonosulfate activation, catalytic mechanism, charge transfer energy, advanced oxidation processes

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