Cited by 73Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Synthesis and Characterization

One‐Step Synthesis of Degradable Vinylic Polymer‐Based Latexes via Aqueous Radical Emulsion Polymerization

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Galanopoulo, Paul, Gil, Noémie, Gigmes, Didier, Lefay, Catherine, Guillaneuf, Yohann, Lages, Maëlle, Nicolas, Julien, Lansalot, Muriel +1 more·2022·Angewandte Chemie International Edition

Abstract

Aqueous emulsion copolymerizations of dibenzo[c,e]oxepane‐5‐thione (DOT) were performed with n‐butyl acrylate (BA), styrene (S) and a combination of both. In all cases, stable latexes were obtained in less than two hours under conventional conditions; that is in the presence of sodium dodecyl sulfate (SDS) used as surfactant and potassium persulfate (KPS) as initiator. A limited solubility of DOT in BA was observed compared to S, yielding to a more homogeneous integration of DOT units in the PS latex. In both cases, the copolymer could be easily degraded under basic conditions. Emulsion terpolymerization between DOT, BA and S allowed us to produce stable latexes not only composed of degradable chains but also featuring a broad range of glass transition temperatures.

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Authors
Galanopoulo, P., Gil, N., Gigmes, D., Lefay, C., Guillaneuf, Y., Lages, M., Nicolas, J., Lansalot, M., & D'Agosto, F.
Affiliations
  • Lyon 1 Université (FR)
  • Centre National de la Recherche Scientifique (FR)
  • Aix-Marseille-Univ Institut de Chimie Radicalaire, Equipe CROPS, CNRS, UMR 7273 Avenue Escadrille Normandie Niemen 13397 Marseille France
  • Univ Lyon, Université Claude Bernard Lyon 1 CPE Lyon, CNRS, UMR 5128 Catalysis, Polymerization, Processes and Materials (CP2M) 43 Bd du 11 novembre 1918 69616 Villeurbanne France
Corresponding author
Lansalot, Muriel
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2022-02-19
Volume
61
Issue
15
Pages
e202117498-e202117498
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W4210517392
Cited by
73
References
27
Citations by year
2026: 12 · 2025: 10 · 2024: 9 · 2023: 27 · 2022: 15
FWCI
5.80
Type
journal article
Language
en
Open access
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
  • HAL (submittedVersion, other-oa)
Funders
Agence Nationale de la Recherche (ANR18, ANR-18-CE06-0014)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
Keywords
butyl acrylate, styrene, terpolymerization, degradable polymers, LaTeX, basic degradation, glass transition temperature, surfactants, potassium persulfate initiator, sodium dodecyl sulfate

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