Cited by 22Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPhotopolymerization techniques and applications

Ring size-reactivity relationship in radical ring-opening copolymerisation of thionolactones with vinyl pivalate

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Ivanchenko, Oleksandr, Mazières, Stéphane, Poli, Rinaldo, Harrisson, Simon, Destarac, Mathias·2022·Polymer Chemistry

Abstract

The radical ring-opening copolymerisation of unsubstituted thionolactones of different ring sizes has been investigated. DFT calculations and experimental results show the importance of the stabilization of the intermediate ring-retained radical.

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Registry

Crossref · 10.1039/d2py01153k

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32 of 32 references verified0 citation errors · 0 not checkable

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  • Very recently, a few reports on radical polymerizations of cyclic thiocarbonyl compounds indicated that some thionolactones were incorporated into a polymer as a mixture of ring-opened and cyclic structures with and without β-scission, depending on the monomer structure and polymerization conditions.

    “Very recently, a few reports on radical polymerizations of cyclic thiocarbonyl compounds indicated that some thionolactones were incorporated into a polymer as a mixture of ring-opened and cyclic structures with and without β-scission, respectively, which depended on the monomer structure and the polymerization conditions.37−39”

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Authors
Ivanchenko, O., Mazières, S., Poli, R., Harrisson, S., & Destarac, M.
Affiliations
Centre National de la Recherche Scientifique (FR)
Corresponding author
  • Harrisson, Simon
  • Destarac, Mathias
Venue
Polymer Chemistry
Published
2022
Volume
13
Issue
45
Pages
6284-6292
ISSN
  • 1759-9954 (ISSN-L)
  • 1759-9962
OpenAlex
W4312697934
Cited by
22
References
31
Citations by year
2026: 6 · 2025: 3 · 2024: 7 · 2023: 6
FWCI
1.52
Type
journal article
Language
en
Open access
Locations
  • Polymer Chemistry (publishedVersion)
  • HAL (submittedVersion, other-oa)
Funders
Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
Keywords
thionolactones, vinyl pivalate, ring size, reactivity ratios, radical stabilization, copolymerization kinetics

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