The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO2 Reduction to CH4
Abstract
Regulating intermediates through elaborate catalyst design to control the reaction direction is crucial for promoting the selectivity of electrocatalytic CO 2‐to‐CH 4. M−C (M=metal) bonds are particularly important for tuning the multi‐electron reaction; however, its construction in nanomaterials is challenging. Here, via rational design of in situ anchoring of Cu SAs (single atoms) on the unique platform graphdiyne, we firstly realize the construction of a chemical bond Cu−C (GDY). In situ Raman spectroelectrochemistry and DFT calculations confirm that due to the fabrication of the Cu−C bond, during CO 2 reduction, the formation of *OCHO intermediates is dominant rather than *COOH on Cu atoms, facilitating the formation of CH 4. Therefore, we find that constructing the Cu−C bond in Cu SAs/GDY can supply an efficient charge transfer channel, but most importantly control the reaction intermediates and guide a more facile reaction pathway to CH 4, thereby significantly boosting its catalytic performance. This work provides new insights on enhancing the selectivity for CO 2 RR at the atomic level.
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Combining theory and experiment in electrocatalysis: Insights into materials design
Seh, Z. W., Kibsgaard, J., Dickens, C. F., Chorkendorff, I., Nørskov, J. K., & Jaramillo, T. F. (2017) · Science · doi:10.1126/science.aad4998 · Cited by 12,114
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F., & Koper, M. T. M. (2019) · Nature Energy · doi:10.1038/s41560-019-0450-y · Cited by 2,747
CO 2 electrolysis to multicarbon products in strong acid
Huang, J. E., Li, F., Ozden, A., Sedighian Rasouli, A., García de Arquer, F. P., Liu, S., Zhang, S., Luo, M., Wang, X., Lum, Y., et al. (2021) · Science · doi:10.1126/science.abg6582 · Cited by 1,359
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
Yin, X., Wang, H., Tang, S., Lu, X., Shu, M., Si, R., & Lu, T. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201804817 · Cited by 594
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Cited by
Jiang, M., Wang, H., Zhu, M., Luo, X., He, Y., Wang, M., Wu, C., Zhang, L., Li, X., Liao, X., et al. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00857f · Cited by 299
Self-citationTwo-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research
Zheng, X., Chen, S., Li, J., Wu, H., Zhang, C., Zhang, D., Chen, X., Gao, Y., He, F., Hui, L., et al. (2023) · ACS Nano · doi:10.1021/acsnano.3c03849 · Cited by 283
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Metadata
- Authors
- Shi, G., Xie, Y., Du, L., Fu, X., Chen, X., Xie, W., Lu, T., Yuan, M., & Wang, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-04-05
- Volume
- 61
- Issue
- 23
- Pages
- e202203569-e202203569
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4220864056
- Cited by
- 222
- References
- 8
- FWCI
- 8.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shi, G., Xie, Y., Du, L., Fu, X., Chen, X., Xie, W., Lu, T., Yuan, M., & Wang, M. (2022). Constructing Cu−C Bonds in a Graphdiyne‐Regulated Cu Single‐Atom Electrocatalyst for CO2 Reduction to CH4. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202203569
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