The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Enhancing Li+ Transport in NMC811||Graphite Lithium‐Ion Batteries at Low Temperatures by Using Low‐Polarity‐Solvent Electrolytes
Open accessAbstract
LiNixCoyMnzO 2 (x+y+z=1)||graphite lithium‐ion battery (LIB) chemistry promises practical applications. However, its low‐temperature (≤ −20 °C) performance is poor because the increased resistance encountered by Li+ transport in and across the bulk electrolytes and the electrolyte/electrode interphases induces capacity loss and battery failures. Though tremendous efforts have been made, there is still no effective way to reduce the charge transfer resistance (Rct) which dominates low‐temperature LIBs performance. Herein, we propose a strategy of using low‐polarity‐solvent electrolytes which have weak interactions between the solvents and the Li+ to reduce Rct, achieving facile Li+ transport at sub‐zero temperatures. The exemplary electrolyte enables LiNi 0.8 Mn 0.1 Co 0.1 O 2||graphite cells to deliver a capacity of ≈113 mAh g−1 (98 % full‐cell capacity) at 25 °C and to remain 82 % of their room‐temperature capacity at −20 °C without lithium plating at 1/3C. They also retain 84 % of their capacity at −30 °C and 78 % of their capacity at −40 °C and show stable cycling at 50 °C.
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In the citing paper
“EMC has a wide liquid temperature range from -53 to 110 °C with a very small dipole moment, which enhances the kinetics and reduces the charge transfer resistance for the desolvation process.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [29]
In the citing paper
“As a result, the graphite-NMC811 pouch cell showed enhanced cyclic stability operating across a wide-temperature range from -40 to 50 °C.”
From Review on Low-Temperature Electrolytes for Lithium-Ion and Lithium Metal Batteries (2023) · cites this paper as [29]
Citations
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Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature
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Self-citationEnabling the Low-Temperature Cycling of NMC||Graphite Pouch Cells with an Ester-Based Electrolyte
Cho, Y.-G., Li, M., Holoubek, J., Li, W., Yin, Y., Meng, Y. S., & Chen, Z. (2021) · ACS Energy Letters · doi:10.1021/acsenergylett.1c00484 · Cited by 162
Cho, Y.-G., Kim, Y.-S., Sung, D.-G., Seo, M.-S., & Song, H.-K. (2014) · Energy Environ. Sci. · doi:10.1039/c3ee43029d · Cited by 85
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Chen, Y.-Q., He, Q., Zhao, Y., Zhou, W., Xiao, P.-T., Gao, P., Tavajohi, N., Tu, J., Li, B.-H., He, X.-M., et al. (2023) · Nature Communications · doi:10.1038/s41467-023-43163-9 · Cited by 239
“…kinetics at the graphite anode were reported to be the main challenge that lowered the potential for Li + intercalationintographitetobelow0V(vs. Li/Li + ) 8,9,25,30 ,whichwasalso evidenced by the much larger impedance of the graphite anode compared to the LCO cathode at LT (Supplementary Fig.”
InfluentialSelf-citationHigh voltage electrolytes for lithium-ion batteries with micro-sized silicon anodes
Li, A., Wang, Z., Pollard, T. P., Zhang, W., Tan, S. L., Li, T., Jayawardana, C., Liou, S., Rao, J., Lucht, B. L., et al. (2024) · Nature Communications · doi:10.1038/s41467-024-45374-0 · Cited by 175
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Kinetic limits and enhancement of graphite anode for fast-charging lithium-ion batteries
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Liang, P., Hu, H., Dong, Y., Wang, Z.-D., Liu, K.-M., Ding, G.-Y., & Cheng, F.-Y. (2024) · Advanced Functional Materials · doi:10.1002/adfm.202309858 · Cited by 120
Metadata
- Authors
- Nan, B., Chen, L., Rodrigo, N. D., Borodin, O., Piao, N., Xia, J., Pollard, T., Hou, S., Zhang, J., Ji, X., Xu, J., Zhang, X., Ma, L., He, X., Liu, S., Wan, H., Hu, E., Zhang, W., Xu, K., Yang, X., Lucht, B., & Wang, C.
- Affiliations
- University of Maryland, College Park (US)
- University of Rhode Island (US)
- DEVCOM Army Research Laboratory (US)
- Department of Chemical and Biomolecular Engineering University of Maryland College Park MD 20742 USA
- University of North Carolina at Charlotte (US)
- Brookhaven National Laboratory (US)
- Corresponding author
- Wang, Chunsheng
- ORCID
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-07-20
- Volume
- 61
- Issue
- 35
- Pages
- e202205967-e202205967
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4283823340
- Cited by
- 222
- References
- 51
- Citations by year
- 2026: 35 · 2025: 58 · 2024: 73 · 2023: 50 · 2022: 6
- FWCI
- 12.79
- Type
- journal article
- Language
- en
- Open access
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Journal of Media Literacy Education (submittedVersion, cc-by)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advancements in Battery Materials
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced Battery Materials and Technologies
- Physical Sciences › Engineering › Automotive Engineering › Battery Modeling and Management
- Keywords
- NMC811, lithium-ion batteries, low-temperature performance, Li+ transport, charge transfer resistance, LiNi0.8Co0.1Mn0.1O2, graphite anode, lithium plating, capacity retention
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