Novel porphyrin‐grafted poly(phenylene vinylene) derivatives: Synthesis and photovoltaic properties
Abstract
A series of novel porphyrin‐grafted poly (phenylene vinylene) derivatives, Porp‐RO‐PPV, were synthesized by a simple two‐step method. These copolymers contain conjugated poly(phenylene vinylene) derivatives as polymer backbone and covalently linked porphyrin units as side chain, which were confirmed by FTIR and 1H NMR, and used for photovoltaic devices. The thermal, optical properties and sensitizing effect, and photovoltaic properties have been investigated. The emission spectra of Porp‐RO‐PPV copolymers revealed the existence of strong energy transfer from PPV backbone to porphyrin units. The energy conversion efficiency (ηe) of photovoltaic devices based on Porp‐RO‐PPV+PCBM reached 0.33% (78.2 mW/cm2, AM1.5) and porphyrin units in the copolymers showed good sensitizing effect at low concentration. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
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Cao et al. synthesized several porphyrin-functionalized copolymers A1-A4 by two-step reactions, and the best PCE of 0.32% was obtained for the A1:PCBM combination.
“Cao et al. synthesized several porphyrinfunctionalized copolymers 24 ( A1 -A4 ) by two-step reactions (Fig. 4), and the best PCE of 0.32% was obtained for the A1 :PCBM combination.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [24]
Emission spectra indicated electron transfer from the PPV backbone to the porphyrin side-chain and then to PCBM.
“Emission spectra indicated electron transfer from the PPV backbone to the porphyrin side-chain and then to PCBM.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [24]
In the A1-A4 copolymers, PCE and Jsc decreased with an increase of porphyrin content.
“However, the PCE and J sc decreased with an increase of porphyrin content in these copolymers.”
From Recent progress in porphyrin-based materials for organic solar cells (2018) · cites this paper as [24]
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- Authors
- Feng, J., Zhang, Q., Li, W., Li, Y., Yang, M., & Cao, Y.
- Affiliations
- Zhejiang University (CN)
- South China University of Technology (CN)
- Corresponding author
- Yang, Mujie
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 2008-05-06
- Volume
- 109
- Issue
- 4
- Pages
- 2283-2290
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2068900233
- Cited by
- 22
- References
- 25
- Citations by year
- 2026: 1 · 2018: 2 · 2017: 1 · 2016: 1 · 2015: 2 · 2014: 3 · 2012: 2
- FWCI
- 2.99
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Applied Polymer Science (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Electronics and Photovoltaics
- Physical Sciences › Materials Science › Materials Chemistry › Porphyrin and Phthalocyanine Chemistry
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Organic Light-Emitting Diodes Research
- Keywords
- poly(phenylene vinylene), copolymers, organic photovoltaic devices, energy transfer, sensitization, PCBM, power conversion efficiency
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