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Infrared spectra and resonance interaction of amide‐I vibration of the antiparallel‐chain pleated sheet

Chirgadze, Yu. N., Nevskaya, N. A.·1976·Biopolymers

Abstract

Theoretical treatment of resonance interaction of amide‐I vibration has been done in a dipole–dipole approximation on the basis of perturbation theory. A single infinite antiparallel‐chain pleated sheet as well as different kinds of its finite fragments have been considered. A good agreement has been obtained between calculated spectral parameters of amide I of the infinite sheet and observed ones in infrared and Raman spectra of synthetic polypeptides and fibrous proteins. A theoretical dependence of the resonance frequency shift of the main component and frequency splitting of two components active in the infrared spectra on the number of polypeptide chains in the finite sheet has been found.

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Metadata

Authors
Chirgadze, Y. N., & Nevskaya, N. A.
Venue
Biopolymers
Publisher
Wiley
Published
1976-04
Volume
15
Issue
4
Pages
607-625
ISSN
  • 0006-3525 (ISSN-L)
  • 1097-0282
OpenAlex
W2132822629
Cited by
311
References
0
FWCI
7.04
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Infrared spectra and resonance interaction of amide‐I vibration of the antiparallel‐chain pleated sheet. https://app.cochat.ai/papers/10.1002/bip.1976.360150402
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Chirgadze, Y. N., & Nevskaya, N. A. (1976). Infrared spectra and resonance interaction of amide‐I vibration of the antiparallel‐chain pleated sheet. Biopolymers. https://doi.org/10.1002/bip.1976.360150402

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