The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Bifunctionality and Mechanism of Electrodeposited Nickel–Phosphorous Films for Efficient Overall Water Splitting
Abstract
Efficient, stable, and low‐cost electrocatalysts are crucial for realizing large‐scale water splitting. Herein, we report that electrodeposited nickel–phosphorous (Ni–P) films can act as efficient bifunctional electrocatalysts for overall water splitting. The as‐prepared Ni–P films exhibit remarkable catalytic performance for both H 2 and O 2 evolution reactions (HER and OER) in alkaline media, achieving a current density of 10 mA cm−2 at overpotentials of −93 mV for HER and 344 mV for OER with Tafel slopes of 43 and 49 mV dec−1, respectively, rivaling the performance of Pt and IrO 2. Various techniques were employed to probe the composition and morphology of the Ni–P films prior to and post catalysis, revealing the major composition of the as‐prepared and post‐HER films as metallic nickel and nickel phosphide, which partially transform to nickel oxides during OER. It was also found that the catalytic rate of OER catalyzed by Ni–P was first order in the activity of the hydroxide anion.
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Cites
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li + -Ni(OH) 2 -Pt Interfaces
Subbaraman, R., Tripkovic, D., Strmcnik, D., Chang, K.-C., Uchimura, M., Paulikas, A. P., Stamenkovic, V., & Markovic, N. M. (2011) · Science · doi:10.1126/science.1211934 · Cited by 3,135
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Highly Active Electrocatalysis of the Hydrogen Evolution Reaction by Cobalt Phosphide Nanoparticles
Popczun, E. J., Read, C. G., Roske, C. W., Lewis, N. S., & Schaak, R. E. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402646 · Cited by 1,240
Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts
Merki, D., & Hu, X. (2011) · Energy & Environmental Science · doi:10.1039/c1ee01970h · Cited by 1,172
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
Kong, D., Cha, J. J., Wang, H., Lee, H. R., & Cui, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42413h · Cited by 1,031
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Cited by
Bifunctional Electrocatalysts for Overall and Hybrid Water Splitting
Quan, L., Jiang, H., Mei, G., Sun, Y., & You, B. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00332 · Cited by 874
Self-citationYou, B., Jiang, N., Sheng, M., Bhushan, M. W., & Sun, Y. (2016) · ACS Catalysis · doi:10.1021/acscatal.5b02193 · Cited by 818
Self-citationYou, B., Jiang, N., Sheng, M., Gul, S., Yano, J., & Sun, Y. (2015) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b02877 · Cited by 631
Self-citationYou, B., Jiang, N., Liu, X., & Sun, Y. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603798 · Cited by 615
Self-citationLi, J., Yan, M., Zhou, X., Huang, Z., Xia, Z., Chang, C., Ma, Y., & Qu, Y. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601420 · Cited by 556
Metadata
- Authors
- Jiang, N., You, B., Sheng, M., & Sun, Y.
- Venue
- ChemCatChem
- Publisher
- Wiley
- Published
- 2015-12-04
- Volume
- 8
- Issue
- 1
- Pages
- 106-112
- ISSN
- 1867-3880 (ISSN-L)
- 1867-3899
- OpenAlex
- W2182511407
- Cited by
- 171
- References
- 19
- FWCI
- 8.11
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jiang, N., You, B., Sheng, M., & Sun, Y. (2016). Bifunctionality and Mechanism of Electrodeposited Nickel–Phosphorous Films for Efficient Overall Water Splitting. ChemCatChem. https://doi.org/10.1002/cctc.201501150
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