The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
In Situ Raman Study of Potential‐Dependent Surface Adsorbed Carbonate, CO, OH, and C Species on Cu Electrodes During Electrochemical Reduction of CO2
Open accessAbstract
Using in situ surface‐enhanced Raman spectroscopy (SERS), and 13 C/12 C and D 2 O/H 2 O isotopic labeling for assignment, we show potential dependent transients in surface composition of Cu‐catalyzed electrochemical reduction of CO 2 in carbonate solution. First, reduction of Cu(I)oxide is accompanied by adsorption of predominantly monodentate carbonate at ∼1067 cm−1 starting in the potential range from [+0.2 V→−0.2 V]. Contrary to recently advocated hypotheses, and based on the significant presence at anodic potential, a band in this potential range at ∼1540 cm−1 can be assigned to bidentate carbonate. As expected, appearance of surface CO was observed in the range of [−0.4 V→−1.0 V], clearly identified by the Cu−CO vibration at 360 cm−1. Most importantly, at the more negative end of this potential range, we identified the formation of surface OH, and for the first time a surface Cu−C species, showing Raman bands at ∼525 cm−1 (Cu−OH) and ∼500 cm−1 (Cu−C), respectively. In the potential range of [−1.0 V→−1.4 V], surface CO disappears, while the Cu−OH and Cu−C species are persistent. Interestingly positive polarization at >0.1 V removes these species and restores the surface to Cu(I)oxide, rendering the surface processes completely reversible. Implications of this study for mechanistic understanding of electrode deactivation and practical operation are discussed.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene
Mistry, H., Varela, A. S., Bonifacio, C. S., Zegkinoglou, I., Sinev, I., Choi, Y.-W., Kisslinger, K., Stach, E. A., Yang, J. C., Strasser, P., et al. (2016) · Nature Communications · doi:10.1038/ncomms12123 · Cited by 1,214
De Luna, P., Quintero-Bermudez, R., Dinh, C.-T., Ross, M. B., Bushuyev, O. S., Todorović, P., Regier, T., Kelley, S. O., Yang, P., & Sargent, E. H. (2018) · Nature Catalysis · doi:10.1038/s41929-017-0018-9 · Cited by 1,046
Subsurface Oxygen in Oxide-Derived Copper Electrocatalysts for Carbon Dioxide Reduction
Eilert, A., Cavalca, F., Roberts, F. S., Osterwalder, J., Liu, C., Favaro, M., Crumlin, E. J., Ogasawara, H., Friebel, D., Pettersson, L. G. M., et al. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b02273 · Cited by 443
Investigating the Role of Copper Oxide in Electrochemical CO 2 Reduction in Real Time
Mandal, L., Yang, K. R., Motapothula, M. R., Ren, D., Lobaccaro, P., Patra, A., Sherburne, M., Batista, V. S., Yeo, B. S., Ager, J. W., et al. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b15418 · Cited by 269
Cited by
Zhan, C., Dattila, F., Rettenmaier, C., Bergmann, A., Kühl, S., García-Muelas, R., López, N., & Cuenya, B. R. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c01478 · Cited by 554
An, H., Wu, L., Mandemaker, L. D. B., Yang, S., de Ruiter, J., Wijten, J. H. J., Janssens, J. C. L., Hartman, T., van der Stam, W., & Weckhuysen, B. M. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202104114 · Cited by 353
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions
Amirbeigiarab, R., Tian, J., Herzog, A., Qiu, C., Bergmann, A., Roldan Cuenya, B., & Magnussen, O. M. (2023) · Nature Catalysis · doi:10.1038/s41929-023-01009-z · Cited by 331
Metadata
- Authors
- Moradzaman, M., & Mul, G.
- Venue
- ChemElectroChem
- Publisher
- Wiley
- Published
- 2021-03-10
- Volume
- 8
- Issue
- 8
- Pages
- 1478-1485
- ISSN
- 2196-0216 (ISSN-L)
- OpenAlex
- W3135508330
- Cited by
- 179
- References
- 5
- FWCI
- 4.14
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: In Situ Raman Study of Potential‐Dependent Surface Adsorbed Carbonate, CO, OH, and C Species on Cu Electrodes During Electrochemical Reduction of CO2. https://app.cochat.ai/papers/10.1002/celc.202001598
- The paper
- Moradzaman, M., & Mul, G. (2021). In Situ Raman Study of Potential‐Dependent Surface Adsorbed Carbonate, CO, OH, and C Species on Cu Electrodes During Electrochemical Reduction of CO2. ChemElectroChem. https://doi.org/10.1002/celc.202001598
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
