Functionalized Magnetic Nanoparticles as New Adsorption Materials for Arsenic Removal from Polluted Waters
Abstract
Abstract BACKGROUND One of the most harmful pollutants to human health present in natural water is arsenic. In this work magnetic silica/magnetite nanoparticles functionalized with aminopropyl groups incorporating Fe3+ (S1‐F3) were investigated for their suitability as materials to adsorb As5+ and As3+ from polluted groundwater. RESULTS Magnetite nanoparticles obtained by a co‐precipitation method were coated with a mesoporous silica layer generated by hydrolysis and condensation of tetraethyl orthosilicate. The resultant material was grafted with amino derivatives coordinated with Fe3+. The synthesis was confirmed by FT‐IR, TGA and BET analyses. After analysis of the affinity of solids with different degrees of functionalization towards arsenate and arsenite species, the material S1‐F3 resulted in maximum arsenic adsorption capacities (14.7 ± 0.3 mg As3+g‐1 and 121 ± 4.1 mg As5+g‐1). The adsorption equilibrium was satisfactorily described by the Langmuir model and exhibited low sensitivity to temperatures in the range 288–308K. Kinetic data were correlated with a pseudo‐second‐order kinetic model based on solid capacity that considers the rate of the surface reaction as the rate‐limiting step. CONCLUSION The promising results confirm that the material S1‐F3 is an effective adsorbent for the removal of arsenate from polluted water. More research is being conducted to analyse the influence of competing anions and sorbent regeneration. © 2014 Society of Chemical Industry.
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The adsorption technique is considered simple and effective and has garnered significant attention in recent studies, particularly for adhesion dyes.
“The adsorption technique, considered for its simplicity and effectiveness, has garnered significant attention in recent studies, particularly in the context of adhesion dyes [18,19].”
From Silica Aerogels as a Promising Vehicle for Effective Water Splitting for Hydrogen Production (2025) · cites this paper as [19]
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- Authors
- Saiz, J., Bringas, E., & Ortiz, I.
- Affiliations
- Universidad de Cantabria (ES)
- Dept. Ingenierías Química y Biomolecular, ETSIIyT Universidad de Cantabria Avda. Los Castros s/n 39005 Santander Spain
- Corresponding author
- Bringas, Eugenio
- ORCID
- Bringas, Eugenio
- Venue
- Journal of Chemical Technology & Biotechnology
- Publisher
- Wiley
- Published
- 2014-05-12
- Volume
- 89
- Issue
- 6
- Pages
- 909-918
- ISSN
- 0142-0356 (ISSN-L)
- 0268-2575
- 1097-4660
- OpenAlex
- W2165044251
- Cited by
- 79
- References
- 66
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 6 · 2023: 6 · 2022: 8 · 2021: 9 · 2020: 5 · 2019: 9 · 2018: 8 · 2017: 4 · 2016: 12 · 2015: 6 · 2014: 2
- FWCI
- 6.10
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Chemical Technology & Biotechnology (publishedVersion)
- Topics
- Physical Sciences › Environmental Science › Environmental Chemistry › Arsenic contamination and mitigation
- Physical Sciences › Environmental Science › Water Science and Technology › Adsorption and biosorption for pollutant removal
- Physical Sciences › Engineering › Biomedical Engineering › Environmental remediation with nanomaterials
- Keywords
- arsenic removal, arsenate adsorption, arsenite adsorption, magnetic nanoparticles, Fe3O4 nanoparticles, silica coating, aminopropyl functionalization, iron(III) coordination, groundwater contamination, adsorption isotherms, adsorption kinetics, water treatment
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