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Preparation of films exhibiting a balanced temperature dependence to permeation by aqueous solutions—a study of lower consolute behavior
Abstract
Temperature dependence of solute transport through aqueously swollen polymeric films and membranes can be altered to show even apparent negative activation energies by the use of polymers exhibiting a lower consolute behavior in solution. The principles by which we constructed a host of such polymers are discussed. A solubility rule is presented which predicts that solutes in water will show a lower critical solution temperature if the proper hydrophilic–hydrophobic balance is achieved.
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Citations
Cited by
In situ-forming hydrogels--review of temperature-sensitive systems
Ruel-Gariépy, E., & Leroux, J.-C. (2004) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2004.03.019 · Cited by 1,297
Vihola, H., Laukkanen, A., Valtola, L., Tenhu, H., & Hirvonen, J. (2005) · Biomaterials · doi:10.1016/j.biomaterials.2004.09.008 · Cited by 689
Thermally on-off switching polymers for drug permeation and release
Okano, T., Bae, Y. H., Jacobs, H., & Kim, S. W. (1990) · Journal of Controlled Release · doi:10.1016/0168-3659(90)90138-j · Cited by 616
Chung, J. E., Yokoyama, M., Yamato, M., Aoyagi, T., Sakurai, Y., & Okano, T. (1999) · Journal of Controlled Release · doi:10.1016/s0168-3659(99)00029-2 · Cited by 599
Moradi Kashkooli, F., Soltani, M., & Souri, M. (2020) · Journal of Controlled Release · doi:10.1016/j.jconrel.2020.08.012 · Cited by 514
Metadata
- Authors
- Taylor, L. D., & Cerankowski, L. D.
- Venue
- Journal of Polymer Science: Polymer Chemistry Edition
- Publisher
- Wiley
- Published
- 1975-11
- Volume
- 13
- Issue
- 11
- Pages
- 2551-2570
- ISSN
- 0360-6376 (ISSN-L)
- 1542-9369
- OpenAlex
- W2046178181
- Cited by
- 597
- References
- 0
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Taylor, L. D., & Cerankowski, L. D. (1975). Preparation of films exhibiting a balanced temperature dependence to permeation by aqueous solutions—a study of lower consolute behavior. Journal of Polymer Science: Polymer Chemistry Edition. https://doi.org/10.1002/pol.1975.170131113
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
