Novel suberin‐based biopolyesters: From synthesis to properties
Abstract
This article reports the successful synthesis and characterization of two types of completely biobased polymers prepared by the polycondensation or polytransesterification of suberin fragments, isolated by different procedures and from two different vegetable sources. These polymerizations were conducted with different experimental conditions in terms of the type of catalyst, the reaction medium and temperature, as well as the molar ratio between the reactive moieties. The ensuing linear or partly crosslinked polyesters were characterized by conventional spectroscopic techniques, SEC, DSC, XRD, DMA, and TGA. These hydrophobic materials represent an original contribution to the growing field of polymers from renewable resources. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011
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A few studies using Bi(OTf)3 to polymerize plant oil- and suberin-derived long-chain fatty acids generated highly crystalline polyesters with high melting and degradation temperatures as attractive alternatives to petroleum-based polyolefins.
“A few studies using Bi(OTf)3 to polymerize plant oil-237 and suberin-derived 238 long-chain fatty acids generated highly crystalline polyesters with high melting and degradation temperatures as attractive alternatives to petroleum-based polyolefins.”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [238]
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Self-citation
- Authors
- Sousa, A. F., Gandini, A., Silvestre, A. J. D., Neto, C. P., Cruz Pinto, J. J. C., Eckerman, C., & Holmbom, B.
- Affiliations
- University of Aveiro (PT)
- Åbo Akademi University (FI)
- Corresponding author
- Gandini, Alessandro
- Venue
- Journal of Polymer Science Part A: Polymer Chemistry
- Publisher
- Wiley
- Published
- 2011-03-28
- Volume
- 49
- Issue
- 10
- Pages
- 2281-2291
- ISSN
- 0887-624X (ISSN-L)
- 1099-0518
- OpenAlex
- W2039932089
- Cited by
- 53
- References
- 29
- Citations by year
- 2026: 1 · 2024: 4 · 2023: 2 · 2022: 4 · 2021: 4 · 2020: 1 · 2019: 2 · 2018: 3 · 2017: 6 · 2016: 7 · 2015: 4 · 2014: 4 · 2013: 6 · 2012: 5
- FWCI
- 1.96
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Polymer Science Part A Polymer Chemistry (publishedVersion)
- Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Plant Surface Properties and Treatments
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
- Keywords
- suberin, biopolyesters, bio-based polymers, polycondensation, renewable resources, hydrophobic polymers, polymer networks, polymer synthesis, polymer characterization
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