Cited by 85biodegradable polymer synthesis and propertiesPolymer crystallization and propertiesPolymer composites and self-healing

Plant Oil‐Based Long‐Chain C26 Monomers and Their Polymers

Vilela, Carla, Silvestre, Armando J. D., Meier, Michael A. R.·2012·Macromolecular Chemistry and Physics

Abstract

The self‐metathesis of erucic acid with ruthenium‐based catalysts, followed by the hydrogenation of the double bond, yielded 1,26‐hexacosanedioic acid (AA). Polycondensation of this biobased long‐chain α,ω‐dicarboxylic acid with hexacosane‐1,26‐diol (BB), generated from the former by reduction, yielded the polyester 26,26. Monomer AA was also polymerized with short‐chain alkanediols, namely dodecane‐1,12‐diol and butane‐1,4‐diol, generating polyesters 12,26 and 4,26, respectively. The properties of these aliphatic polyesters were investigated by various techniques, revealing high crystallinity, melting, and degradation temperatures, depending on the monomers used. These materials are an attractive alternative to fossil resource‐based polymeric materials.

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Crossref · 10.1002/macp.201200332

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45 of 45 references verified0 citation errors · 0 not checkable

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  • SGP of plant oils derived diols and diacids with > 20 methylene sequences generates polyesters with structures and thermal properties reminiscent of PE.

    “For example, SGP of plant oils derived diols and diacids with > 20 methylene sequences generates polyesters with structures and thermal properties reminiscent of PE. 213”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [213]

  • A few studies using Bi(OTf)3 to polymerize plant oil- and suberin-derived long-chain fatty acids generated highly crystalline polyesters with high melting and degradation temperatures as attractive alternatives to petroleum-based polyolefins.

    “A few studies using Bi(OTf)3 to polymerize plant oil-237 and suberin-derived 238 long-chain fatty acids generated highly crystalline polyesters with high melting and degradation temperatures as attractive alternatives to petroleum-based polyolefins.”

    From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [237]

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Authors
Vilela, C., Silvestre, A. J. D., & Meier, M. A. R.
Affiliations
  • Karlsruhe Institute of Technology (DE)
  • University of Aveiro (PT)
Venue
Macromolecular Chemistry and Physics
Publisher
Wiley
Published
2012-08-31
Volume
213
Issue
21
Pages
2220-2227
ISSN
  • 1022-1352 (ISSN-L)
  • 1521-3935
OpenAlex
W2067049331
Cited by
85
References
45
Citations by year
2026: 2 · 2025: 5 · 2024: 9 · 2023: 1 · 2022: 2 · 2021: 8 · 2020: 2 · 2019: 4 · 2018: 4 · 2017: 7 · 2016: 7 · 2015: 10 · 2014: 13 · 2013: 10 · 2012: 1
FWCI
4.41
Type
journal article
Language
en
Open access
closed
Locations
Macromolecular Chemistry and Physics (publishedVersion)
Topics
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer composites and self-healing
Keywords
erucic acid, self-metathesis, ruthenium catalysts, aliphatic polyesters, polycondensation, alkanediols, crystallinity, thermal degradation, bio-based polymers

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