Synthesis of aliphatic suberin-like polyesters by ecofriendly catalytic systems
Abstract
A rapid and ecofriendly microwave assisted p-dodecylbenzenesulfonic acid (DBSA) emulsion polycondensation of long-chain suberin model comonomers was successfully carried out for the first time. Microwave irradiation reduced drastically the reaction time to only 15 min, compared with the DBSA/water polycondensation under conventional heating. Bulk polycondensation using CALB lipase or Bi(OTf) 3 were also carried out with isolation yields up to 93% and number-average molecular weights up to around 7300.
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This mild and environmentally benign system has been successfully applied to several fatty-acid type monomers.
“This mild and environmentally benign system has been successfully applied to several fatty-acid type monomers.253,254”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [253]
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Self-citation
- Authors
- Sousa, A. F., Silvestre, A. J. D., Gandini, A., & Neto, C. P.
- Affiliations
- University of Aveiro (PT)
- Corresponding author
- Sousa, Andreia F.
- Venue
- High Performance Polymers
- Publisher
- SAGE Publications
- Published
- 2012-02
- Volume
- 24
- Issue
- 1
- Pages
- 4-8
- ISSN
- 0954-0083 (ISSN-L)
- 1361-6412
- OpenAlex
- W2112931442
- Cited by
- 29
- References
- 22
- Citations by year
- 2022: 2 · 2021: 2 · 2020: 1 · 2018: 1 · 2017: 5 · 2016: 6 · 2015: 3 · 2014: 5 · 2013: 3 · 2012: 1
- FWCI
- 1.56
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- High Performance Polymers (publishedVersion)
- Portuguese National Funding Agency for Science, Research and Technology (RCAAP Project by FCT) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Life Sciences › Agricultural and Biological Sciences › Plant Science › Plant Surface Properties and Treatments
- Physical Sciences › Chemistry › Organic Chemistry › Microwave-Assisted Synthesis and Applications
- Keywords
- aliphatic polyesters, microwave-assisted polycondensation, biocatalysis, green chemistry
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