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Cited by 256

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Vertically Oriented 2D Layered Perovskite Solar Cells with Enhanced Efficiency and Good Stability

Zhang, Xinqian, Wu, Gang, Yang, Shida, Fu, Weifei, Zhang, Zhongqiang, Chen, Chen, Liu, Wenqing, Yan, Jielin, Yang, Weitao, Chen, Hongzheng·2017·Small

Abstract

Vertically oriented highly crystalline 2D layered (BA)2(MA)n−1 PbnI 3n+1 (BA = CH 3(CH 2)3 NH 3, MA = CH 3 NH 3, n = 3, 4) perovskite thin‐films are fabricated with the aid of ammonium thiocyanate (NH 4 SCN) additive through one‐step spin‐coating process. The humidity‐stability of the film is certified by the almost unchanged X‐ray diffraction patterns after exposed to humid atmosphere (Hr = 55 ± 5%) for 40 d. The photovoltaic devices with the structure of indium tin oxide(ITO)/poly(3,4‐ethylenedioxythiophene):poly(styrene‐sulfonate)/(BA)2(MA)n−1 PbnI 3n+1(n = 3,4)/[6,6]‐phenyl‐C 61‐butyric acid methyl ester/Bathocuproine/Ag are fabricated. The devices based on (BA)2(MA)2 Pb 3 I 10 perovskite (n = 3) with the precursor composition of BAI:methylammonium iodide:PbI 2:NH 4 SCN = 2:2:3:1 (by molar ratio) show an averaged power conversion efficiency (PCE) of 6.82%. In the case of (BA)2(MA)3 Pb 4 I 13 (n = 4), a higher PCE of 8.79% is achieved. Both of the unsealed devices perform unique stability with almost unchanged PCE during the period of storage in purified N 2 glove box. This work provides a simple and effective method to enhance the efficiency of the 2D perovskite solar cell.

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Metadata

Authors
Zhang, X., Wu, G., Yang, S., Fu, W., Zhang, Z., Chen, C., Liu, W., Yan, J., Yang, W., & Chen, H.
Venue
Small
Publisher
Wiley
Published
2017-07-10
Volume
13
Issue
33
ISSN
  • 1613-6810 (ISSN-L)
  • 1613-6829
OpenAlex
W2735830284
Cited by
256
References
2
FWCI
13.76
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Vertically Oriented 2D Layered Perovskite Solar Cells with Enhanced Efficiency and Good Stability. https://app.cochat.ai/papers/10.1002/smll.201700611
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Zhang, X., Wu, G., Yang, S., Fu, W., Zhang, Z., Chen, C., Liu, W., Yan, J., Yang, W., & Chen, H. (2017). Vertically Oriented 2D Layered Perovskite Solar Cells with Enhanced Efficiency and Good Stability. Small. https://doi.org/10.1002/smll.201700611

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