The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Ultrathin Porous NiFeV Ternary Layer Hydroxide Nanosheets as a Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting
Open accessAbstract
Herein, the hydrothermal synthesis of porous ultrathin ternary NiFeV layer double hydroxides (LDHs) nanosheets grown on Nickel foam (NF) substrate as a highly efficient electrode toward overall water splitting in alkaline media is reported. The lateral size of the nanosheets is about a few hundreds of nanometers with the thickness of ≈10 nm. Among all molar ratios investigated, the Ni 0.75 Fe 0.125 V 0.125‐LDHs/NF electrode depicts the optimized performance. It displays an excellent catalytic activity with a modest overpotential of 231 mV for the oxygen evolution reaction (OER) and 125 mV for the hydrogen evolution reaction (HER) in 1.0 m KOH electrolyte. Its exceptional activity is further shown in its small Tafel slope of 39.4 and 62.0 mV dec−1 for OER and HER, respectively. More importantly, remarkable durability and stability are also observed. When used for overall water splitting, the Ni 0.75 Fe 0.125 V 0.125‐LDHs/NF electrodes require a voltage of only 1.591 V to reach 10 mA cm−2 in alkaline solution. These outstanding performances are mainly attributed to the synergistic effect of the ternary metal system that boosts the intrinsic catalytic activity and active surface area. This work explores a promising way to achieve the optimal inexpensive Ni‐based hydroxide electrocatalyst for overall water splitting.
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Cited by
Jiang, J., Sun, F., Zhou, S., Hu, W., Zhang, H., Dong, J., Jiang, Z., Zhao, J., Li, J., Yan, W., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-05341-y · Cited by 1,020
Yang, Y., Yao, H., Yu, Z., Islam, S. M., He, H., Yuan, M., Yue, Y., Xu, K., Hao, W., Sun, G., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b04492 · Cited by 911
Defect engineering in thermoelectric materials: what have we learned?
Zheng, Y., Slade, T. J., Hu, L., Tan, X. Y., Luo, Y., Luo, Z.-Z., Xu, J., Yan, Q., & Kanatzidis, M. G. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00347j · Cited by 482
Self-citationPorous Two-Dimensional Materials for Photocatalytic and Electrocatalytic Applications
Wang, H., Liu, X., Niu, P., Wang, S., Shi, J., & Li, L. (2020) · Matter · doi:10.1016/j.matt.2020.04.002 · Cited by 435
Ir–O–V Catalytic Group in Ir-Doped NiV(OH)2 for Overall Water Splitting
Li, S., Xi, C., Jin, Y.-Z., Wu, D., Wang, J.-Q., Liu, T., Wang, H.-B., Dong, C.-K., Liu, H., Kulinich, S. A., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.9b01252 · Cited by 182
Metadata
- Authors
- Dinh, K. N., Zheng, P., Dai, Z., Zhang, Y., Dangol, R., Zheng, Y., Li, B., Zong, Y., & Yan, Q.
- Venue
- Small
- Publisher
- Wiley
- Published
- 2017-12-27
- Volume
- 14
- Issue
- 8
- ISSN
- 1613-6810 (ISSN-L)
- 1613-6829
- OpenAlex
- W2778171357
- Cited by
- 373
- References
- 41
- FWCI
- 10.10
- Type
- journal article
- Language
- en
- Open access
- green
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- Dinh, K. N., Zheng, P., Dai, Z., Zhang, Y., Dangol, R., Zheng, Y., Li, B., Zong, Y., & Yan, Q. (2018). Ultrathin Porous NiFeV Ternary Layer Hydroxide Nanosheets as a Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting. Small. https://doi.org/10.1002/smll.201703257
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